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- How did Emil Bayer manage to make the bark of the Willow Tree that contained the active ingredient and precursor to aspirin LESS acidic via his organic chemistry reaction. Be specific, show by chemical reaction and circle all functional groups (parts of the molecule) in the reactants that were altered in the products (circle these too.When aspirin is made from acetic acid, the by product is H2O; when acetic anhydride 1Sused, the by-product is acetic acid. When acetyl chloride is used (see above), the by product is HC1. Which route should you use if you were working for Leica, a company that mass produces aspirin on a daily basis? Why?Predict the products of the following Acid/Base reactions. Determine if each one is a Lewis or Bronstead Lowery reaction. 1. This reaction would be best described as __________ A/B reaction. Explain. 2. This reaction would be best described as __________ A/B reaction. Explain. In the Lewis A/B reaction above label the nucleophile and electrophile. What is a positively charged carbon called? Is this a Lewis acid or Lewis base? Explain.
- Please don't ptovide handwritten solution ....3. You are given a mixture of aspirin, phenol, and naphthalene that you need to separate. i) Draw the structures of each, and identify if they are acidic, basic, or neutral compounds. For each compound draw their reaction with the appropriate acidic or basic conditions that will change their solubility and allow them to be separated. ii) What modifications would you have to make to the experimental protocol in order to separate these three compounds? Provide specifics.When water is the solvent, the pKa of acetic acid (CH3CO2H) is 4.75, but when DMSO is the solvent, the pKa is 12.6.Explain why. Hint: Review Section 2.9 and consider the ability of each solvent to solvate cations and anions.
- Match the unknowns with their correct class of organic compounds based on the given qualitative tests below. Unkown A Unkown B Unkown C Unkown D Choices: I. Ester II. Amide III. Acid anhydride IV. Acid halideAfter your liquid-liquid extraction, you added concentrated acid solution to each of your basic aqueous solutions. How does the acid help with recovery of the desired compounds? Options: It protonates the compounds to make them neutral, so they can be extracted back into organic solvents It removes excess base from the solution It makes the compounds into salts It neutralizes the solutionANSWER ALL AND WILL GIVE YOU THUMBS UP AND RATE YOU GOOD Classify the following examples to the given agents. CHOICES: Suspending agent Emulsifying agent QUESTIONS: Bentonite Kaolin Lecithin Carbomer Polysorbate 20 Carrageenan Methyl cellulose Ceteareth 20 Tragacanth Mustard
- Please don't epovide hand written solution.....Why do you wash the dichloromethane solution of your reductive amination product with sodium bicarbonate, rather than dilute aqueous HCl? a) Sodium bicarbonate is a good method of removing aldehydes from organic solvent.b) The amine product will be protonated by acid and remain in the aqueous layer as a salt.c) Sodium bicarbonate transfers the amine starting material into the aqueous layer.d) Sodium bicarbonate reacts with leftover NaBH(OAc)3 and removes it from the mixture.a) Put these three common types of carbonyl compound in order of decreasing reactivity ester amide acid chloride b) For the least reactive, show the interconversion to its other resonance form: How does this electron delocalisation make it stable? c) For the most reactive, draw the mechanism of its undergoing hydrolysis (reaction with H2O): Why makes this type of carbonyl so reactive to nucleophiles?