Why are the observed configurations of, for example, trigonal bipyramidal structures  sometimes different for different measuring techniques?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter21: The Solid State: Crystals
Section: Chapter Questions
Problem 21.52E
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Why are the observed configurations of, for example, trigonal bipyramidal structures 
sometimes different for different measuring techniques? 

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