Why is adsorption always exothermic?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter22: Surfaces
Section: Chapter Questions
Problem 22.46E: Early attempts to coat metals with Teflon, poly tetrafluoroethylene, resulted in a polymer layer...
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Why is adsorption always exothermic?

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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,