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Why is o-fluorobenzoic acid the weakest of the ortho-halo-substituted benzoic acids?
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- Why can aryl halides not be prepared by reaction of phenol with HCl in the presence of ZnCl2?How to Determine the Relative Acidity of SubstitutedBenzoic Acids ?Why are fewer resonance structures for the carboxylate more effective at increasing the acidity of a carboxylic acid than those of the conjugate base of 2-naphthol?
- What is the difference between the reaction that occurs when isopropyltrimethylammonium hydroxide is heated and the reaction that occurs when 2-bromopropane is treated with hydroxide ion?Which has a lower pKa value, the conjugate acid of 3-bromoquinuclidine or the conjugate acid of 3 -chloroquinuclidine?Why are 2-nitrobenzoic acid and 2-chlorobenzoic acid stronger acids than benzoic acid? Aromatic Side-Chain Oxidation: o-Chlorobenzoic Acid from o-Chlorotoluene
- Arrange the 3 carboxylic acids below in the order of increasing acidity and explain why you have arranged them in that order: 3-chloropentanoic acid, 4-fluoroheptanoic acid, 3-iodopentanoic acidExplain this statement: Although 2-methoxyacetic acid (CH3OCH2COOH) is a stronger acid than acetic acid (CH3COOH), p-methoxybenzoic acid (CH3OC6H4COOH) is a weaker acid than benzoic acid (C6H5COOH).Explain this statement: Although 2-methoxyacetic acid (CH3OCH2COOH)is a stronger acid than acetic acid (CH3COOH), p-methoxybenzoic acid(CH3OC6H4COOH) is a weaker acid than benzoic acid (C6H5COOH).