Why is the below reaction split into two independent rate stages. The overall reaction between hydrogen peroxide and iodide ion in acid solution is: H2O2 + 2H* + 3I- 2H,O + Iz I2 + I The kinetics of this reaction has been interpreted as consisting of two independent rate determining stages: k,° H2O2 + I H2O + IO¯ (1) k1 H2O2 + H* + I H20 + HIO (2)

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 68QAP: For the decomposition of a peroxide, the activation energy is 17.4 kJ/mol. The rate constant at 25C...
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Why is the below reaction split into two independent
rate stages.
The overall reaction between hydrogen peroxide and iodide ion in acid solution is:
H2O2 + 2H* + 31-
2H,O + I;
I, + I
The kinetics of this reaction has been interpreted as consisting of two independent rate
determining stages:
H2O2 + I
H20 + IO-
(1)
k1
H2O2 + H* + I
Н.О + HIO
Transcribed Image Text:Why is the below reaction split into two independent rate stages. The overall reaction between hydrogen peroxide and iodide ion in acid solution is: H2O2 + 2H* + 31- 2H,O + I; I, + I The kinetics of this reaction has been interpreted as consisting of two independent rate determining stages: H2O2 + I H20 + IO- (1) k1 H2O2 + H* + I Н.О + HIO
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