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- According to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?Sodium bicarbonate (baking soda), NaHCO3, can be purified by dissolving it in hot water (60 C), filtering to remove insoluble impurities, cooling to 0 C to precipitate solid NaHCO3, and then filtering to remove the solid, leaving soluble impurities in solution. Any NaHCO3 that remains in solution is not recovered. The solubility of NaHCO3 in hot water of 60 C is 164 g/L. Its solubility in cold water of 0 C is 69 g/L. What is the percent yield of NaHCO3 when ills purified by this method?A student set up an experiment for six different trials of the reaction between 1.00-M aqueous acetic acid, CH3COOH, and solid sodium hydrogen carbonate, NaHCO3. CH3COOH(aq) + NaHCO3(s) NaCH3CO2(aq) + CO2(g) + H2O() The volume of acetic acid was kept constant, but the mass of sodium bicarbonate increased with each trial. The results of the tests are shown in the figure. (a) In which trial(s) is the acetic acid the limiting reactant? (b) In which trial(s) is sodium bicarbonate the limiting reactant? (c) Explain your reasoning in parts (a) and (b).
- 4.65 Using the web, find out how lead “poisons” the catalyst in a catalytic converter.Nickel(II) sulfide, NiS, occurs naturally as the relatively rare mineral millerite. One of its occurrences is in meteorites. To analyze a mineral sample for the quantity of NiS, the sample is dissolved in nitric add to form a solution of Ni(NO3)2. NiS(s) + 4 HNO3(aq) Ni(NO3)2(aq) + 2 NO2(g) + 2 H2O(l) + S(s) The aqueous solution of Ni(NO3)2 is then reacted with the organic compound dimethylglyoxime (C4H8N2O2) to give the red solid Ni((C4H7N2O2)2. Ni(NO3)2(aq) + 2 (C4H8N2O2)(aq) Ni(C4H7N2O2)2 + 2 HNO3(aq) Suppose a 0.468-g sample containing millerite produces 0.206 g of red, solid Ni(C4H7N2O2)2 What is the mass percent of NiS in the sample?Many over-the-counter antacid tablets are now formulated using calcium carbonate as the active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting the stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a “burp”). Write the unbalanced chemical equation for this process.
- On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?Chlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is NaCl(aq)+H2SO4(aq)+MnO2(s)Na2SO4(aq)+MnCl2(aq)+H2O(l)+Cl2(g) Balance this equation.3.88 One Step in the enrichment of uranium for use in nuclear power plants involves the reaction of UO2 with hydro- fluoric acid (HF) solution. The products are solid UF4 and water. Write a balanced chemical equation for this reaction.
- Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?Copper metal can reduce silver ions to metallic silver. The copper is oxidized to copper ions according to the reaction 2Ag+(aq)+Cu(s)Cu2+(aq)+2Ag(s)A copper strip with a mass of 2.00 g is dipped into a solution of AgNO3. After some time has elapsed, the copper strip is coated with silver. The strip is removed from the solution, dried, and weighed. The coated strip has a mass of 4.18 g. What are the masses of copper and silver metals in the strip? (Hint: Remember that the copper metal is being used up as silver metal forms.)