Write a possible structure for the compound with formula C3H6O, where meet the following conditions: A. Two of the carbons form a double bond b. The oxygen is bound between two of the carbons c. Oxygen and the three carbons form a cyclic compound.
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Organomagnesium compounds
The interaction of alkyl halide with Mg metal in a suitable ether solvent is the common method for the synthesis of the Grignard reagent.
Hydrolysis Grignard Reactions and Reduction
Organomagnesium halides are Grignard reagents. Francois Auguste Victor Grignard, a French chemist who received the Nobel Prize in Chemistry in 1912, created these highly useful reagents.
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- One of the products of petroleum refinery is naphtha where, benzene could beobtained via catalytic reforming of naphtha. The obtained benzene can potentiallyto react with Lewis acid to form new carbon-carbon bond. Propose the startingmaterial and stepwise mechanism to produce new chemical structure which consista formula molecule of C11H16.Compound A(C10H12O)gives off oxygen on treatment with sodium metal and also decolorizes Br2 in CCl4 to give organic compound B. Compound A on treatment with I2 in NaOH gives iodoform and salt C which after acidification gives a white solid D(C7H6O2). Using knowledge of organic chemistry identify structures A,B,C and DFor following substituted benzenes: [1] C6H5Br; [2] C6H5CN; [3] C6H5OCOCH3: On balance, does the substituent make a benzene ring more or lesselectron rich than benzene itself?
- An organic compound A which has a characteristic odour is treated with 50% NaOH to give B (C7H8O)and C which is a sodium salt of an organic acid . Oxidation of B gives back A. Heating C with soda lime yields an aromatic hydrocarbon D . Deduce the structures of A,B,C and DChemistry The following chemical trabsformation: the alkene compound X can be isomerized to compound Y by treatment with TsOH. Please draw a detailed stepwise reaction mechanism using arrows to indicate the electron flows.An unknown hydrocarbon A with the formula C6H12 reacts with 1 molar equivalent ofH2 over a palladium catalyst. Hydrocarbon A also reacts with OsO4 to give diol B. When oxidized with KMnO4 in acidic solution, A gives two fragments. One fragmentis propanoic acid, CH3CH2CO2H, and the other fragment is ketone C. What are thestructures of A, B, and C? Write all reactions and show your reasoning.
- Compound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentaneCompound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane (i) Draw the structural formula of compounds K, L and M.Compound K, L and M are three isomers with the molecular formula C5H10O.Compound K cannot be oxidized, while compound M and L can be oxidized.Oxidation of compound L with hot acidified potassium permanganate,KMnO4 solution yields 2-methylbutanoic acid. When treated with Iodoformreagent, yellow precipitation only occurs in compound K. Fehling test onlyyielded positive results for compound L and negative for compound M andK. Compound M is then reacted with hydrogen chloride, HCl produceschlorocyclopentane. (ii) Name the type of chemical reaction of compound M when reacted withhydrogen chloride, HCl .
- Rank the following groups in order of decreasing priority. −F, −NH2, −CH3, −OHCompound A is an alcohol that undergoes oxidation to produce compound B.Compound B is a ketone that gives positive triiodomethane reaction. Compound B isthen reacted with phenyl magnesium bromide, C6H5MgBr in the presence of aqueousacid to form compound C. Compound C has the molecular formula of C9H12O. Deducethe structure for compound A, B and C. PLEASE PROVIDE CLEAR DRAWINGS AND EXPLANATIONSA, a compound with molecular formula C6H10, contains three methylene units. A reacts with one equivalent of H2 over Pd/C to yield B. A reacts with aqueous acid to form a single product, C, and undergoes hydroboration/oxidation to form a pair of enantiomers, D and E. Ozonolysis of A followed by reaction with dimethyl sulfide forms F with molecular formula C6H10O2. Provide structures for A–F.