Answered: Write the equations involved in the…

Science

Chemistry

Write the equations involved in the following reactions:(i) Williamson ether synthesis(ii) Kolbe’s reaction

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.4: Substituent Effects In Electrophilic Substitutions

Problem 9P: Predict the major products of the following reactions: (a) Nitration of bromobenzene (b) Bromination...

See similar textbooks

Related questions

Q: Give the reagents and reaction conditions for the conversion of (i), (ii), (iii), (iv) and (v)…

Q: Compound A was oxidized with periodic acid to give B, which after acid hydrolysis gave C. Bromine…

A: Compound A on treatment with periodic acid produces compound B and glyoxal.

Q: Starting with the following compounds, outline a practical synthesis of 1-butanol: 1. 2-chlorobutane…

A: Given, 1. 2-chlorobutane -----> 1-butanol 2. 1-butyne -------> 1-butanol

Q: Provide the reagents necessary to carry out the following conversion: но

Q: Suggest process and compounds required to synthesis 2-methyl-2-hexanol from each compound.

A: synthesis of 2-methyl-2-hexanol from each given compounds:

Q: show how a Grignard reagent, X, is synthesized

A: A Grignard reagent or Grignard compound is a chemical compound with the generic formula R−Mg−X,…

Q: Starting with acetylene and ethylene oxide as the only sources of carbon atoms, show how to prepare…

A: Q) Preparation of Hexanediol:

Q: Compound A (C,H12) absorbed 3 equivalents of H2 on catalytic reduction over a palladium catalyst to…

Q: What condensation products would you expect to obtain by treatment of Ethyl butanoate with sodium…

Q: Sketch and explain the IR, UV, mass, and NMR (1H and 13C) spectroscopy data of Benzonitrile

A: There are different types of spectroscopic techniques for the identification and characterisation of…

Q: Write a mechanism that accounts for the formation of ethyl isopropyl ether as one of the products in…

A: Addition reactions are basically the reaction in which addition of any nucleophile or electrophile…

Q: Write the etherification reactions of isopropyl bromide and 2-bromo-1-nitropropane with phenol .…

Q: Describe the structure of the methylethium tetramer (including the orbitals involved in the bonds)…

A: Methyl lithium tetramer Li4 (CH3)4is an organometallic compound. This tetramer is an example of…

Q: (a) Write the structures of main products when aniline reacts with the following reagents :(i) Br2…

A: Aniline is basic in nature and act as nucleophile More hydrogen bonding more will be it's boiling…

Q: Suggest short, efficient reaction sequences suitable to produce the compound from the given starting…

A: Benzyl methyl ether can be prepared by the reaction of benzaldehyde dimethyl acetal and…

Q: What is the purpose of HCl in the iodination of vanillin. And what is the complete mechanism for…

Q: 3. Upon treatment with aqueous acid, compound 1 is converted into compound 2.

Q: o - Nitroaniline is more soluble in ethanol than p - nitroaniline. Propose a scheme by which a pure…

A: o - Nitroaniline is more soluble in ethanol than p - nitroaniline.

Q: Describe two synthetic routes for the preparation of p-methoxyaniline from benzene.

A: Nitration Process of attaching nitro group to the molecule is called as nitration reaction.…

Q: II. Explain through the use of general reactions and brief statements the following phenomena: a How…

A: The carbonyl compounds (aldehydes or ketones) on treatment with LiAlH4 or catalytic reduction…

Q: Which of the following results would we look for if we were to distinguish the two compounds below…

A: The compound at the left hand side has olefinic double bond that is not the part of the aromatic pi…

Q: The following tests or reagents could differentiate 2,3-dimethylheptane and…

Q: Write the equations involved in the following reactions:(i) Reimer-Tiemann reaction(ii) Williamson’s…

A: Reimer- Tiemann reaction- Formylation of phenols with chloroform in alkaline solution is known as…

Q: Provide the reagents necessary to carry out the following conversion. ОН

Q: 1. Phenylamine (CoHsNH2) is a brown liquid. 1 It is insoluble in water but soluble in dilute acids 2…

A: we have to determine correct statement about phenylamine.

Q: Outline a mechanism for the dehydration of 4-methylcyclohexanol catalyzed by phosphoric acid.

A: To write a mechanism for the dehydration of 4-methylcyclohexanol catalyzed by phosphoric acid.…

Q: (a) Write chemical equations to illustrate the following name bearing reactions :(i) Cannizzaro’s…

A: Given reactions are : (i). Cannizzaro’s reaction (ii). Hell-Volhard-Zelinsky reaction Reactions = ?…

Q: Write the sequence of steps required for the conversion of benzene into benzenediazonium chloride.

A: Benzene diazoniumchloride can be prepared by benzene. The process involve the formation of…

Q: 1a. Give a detailed, stepwise mechanism for the Fischer esterification of acetic acid with methanol.…

A: Reaction involves following steps: Protonation Attack if nucleophile Deprotonation Dehydration

Q: Suggest a synthetic strategy for the synthesis of 6-methyl-3-heptanol from 4-methylpentanenitrile,…

Q: Suggest a reasonable series of reagents and reactions conditions to prepare cis-2-methylcyclohexly…

A: In the reactant, both Me and OH groups are present at axial position. At first OH group is oxidized…

Q: 1. 2-chlorobutane 2. 1-butyne

A: 1. 2-chorobutane ----> 1-butanol 2. 1- butyne --------> 1- butanol

Q: What condensation products would you expect to obtain by the treatment of 3 - Phenylpropanal with…

A: Here we have to find out the condensation products obtained from reaction between 3-Phenylpropanal…

Q: we know that ethers, such as diethyl ether and tetrahydrofuran, are quite resistant to the action of…

A: Main difference in chemical reactivity toward dilute aqueous acid between ethers and acetals:

Q: Provide the reagents necessary to carry out the following conversion.

A: Given,

Q: (a) Give chemical tests to distinguish between :(i) Propanol and propanone (ii)…

A: (a) (i) The given compounds are propanol and propanone. Propanol is an alcohol. Propanone is a…

Q: Compound A has the molecular formula C14H25Br and was obtained by reaction of sodium acetylide…

A: Given, Molecular formula of compound A = C14H25Br Compound B = C14H24 Compound C = C14H26 Compound D…

Q: Use line structures and write the mechanism for the first and second steps of the hydrobromination…

Q: What are the names of the compound A, B, C, D, E, F, G & H. Hence suggest structures for compound C…

Q: Provide answer to the attached file

A: As per the company’s rules, only the first question can be answered.

Q: Compound EE, C5H10O gives a positive result (formation of silver mirror) when reacted with Tollen’s…

Q: z When (R)-2-butanol is left standing in aqueous acid, it slowly loses its optical activity. Account…

A: The overall reaction is as follows,

Q: Write a mechanism for the formation of tert-butylbenzene from benzene and tert-butyl alcohol in the…

A: Electrophilic addition The reaction in which benzene reacts with an electrophile and form addition…

Q: Doxaprost, an orally active bronchodilator patterned after the natural prostaglandins , is…

Q: Provide the missing reagent necessary to carry out the following conversion. |1) H2 / Lindlar…

A: Alkynes have very similar reactions to alkenes. They are susceptible to electrophilic additions such…

Question

Write the equations involved in the following reactions:
(i) Williamson ether synthesis
(ii) Kolbe’s reaction

Definition Definition Organic reaction in which an organohalide and a deprotonated alcohol forms ether. The formation of ether in this synthesis is an S N 2 reaction.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

General Physical Properties of Organic Compounds

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Mention and Write the following reaction mechanisms: a) thermal dehydration of 4-t-butylcyclohexanol with phosphoric acid as catalyst; b) addition of molecular bromine to the C= C double bond of 4-t- butylcyclohexene;
Sketch and explain the IR, UV, mass, and NMR (1H and 13C) spectroscopy data of benzaldehyde.
Write the equations involved in the following reactions:(i) Reimer-Tiemann reaction(ii) Williamson’s ether Synthesis
Doxaprost, an orally active bronchodilator patterned after the natural prostaglandins , is synthesized in the following series of reactions starting with ethyl 2-oxocyclopentanecarboxylate. Except for the Nef reaction in Step 8, we have seen examples of all other types of reactions involved in this synthesis. Q. Write equations to show that Step 6 can be brought about using either methanol or diazomethane (CH2N2) as a source of the -CH3 in the methyl ester.
What products would you would expect to obtain when the following compounds react with ozone and then with dimethylsulfide?
Which of the following results would we look for if we were to distinguish the two compounds below by addition of the mentioned reagents/subjecting the compounds to the reactions? a. Decolorization of KMnO4 b. Decolorization of Br2 in light c. Decolorization of AlCl3 when reacted with the compound and Br2 d. Yellow, sooty flame under combustion
Starting with the following compounds, outline a practical synthesis of 1-butanol
z When (R)-2-butanol is left standing in aqueous acid, it slowly loses its optical activity. Account for this observation
Sketch and explain the IR, UV, mass, and NMR (1H and 13C) spectroscopy data of Benzonitrile
Compound A has the molecular formula C14H25Br and was obtained by reaction of sodium acetylide (HC≡CNa) )with 1,12-dibromododecane. On treatment of compound A with sodium amide, it was converted to compound B (C14H24). Ozonolysis of compound B gave the diacid HO2C(CH2)12CO2H. Catalytic hydrogenation of compound B over Lindlar palladium gave compound C (C14H26), while hydrogenation over platinum gave compound D (C14H28). Sodium-ammonia reduction of compound B gave compound E (C14H26). Both C and E yielded O═CH(CH2)12CH═O on ozonolysis. Assign structures to compound A through E so as to be consistent with the observed transformations.
1. Compound A, C9H12, absorbs 3 equivalents of H2 on catalytic hydrogenation over palladium catalyst to give B, C9H18. On the treatment with acidic KMnO4, compound A gives among other things, a ketone that was identified as cyclohexanone. On reaction with NaNH2 in NH3, followed by addition of iodomethane, compound A gives a new hydrocarbon C, C10H14. What are the structures of A , B and C?
1.Describe the ozonolysis of alkenes 2.one mole of a hydrocarbon(A) reacts with one mole of beomine giving a dibromo compound C5H10Br2.Substance A on treatment with cold dilute kMnO4 solution forms a compound C5C12O2(C5H12O2) on ozonolysis A,gives equimolar quantities of propanone and ethanol.Deduce the structure of substance A.