Write the MAJOR product(s) of the following reactions: H2C: ECH- EN + а. OH c=0 H3C-CH=CH FCH= CH FCH3 + H. b. H3C

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions
Section19.9: Nucleophilic Addition Of Hydrazine: The Wolff–kishner Reaction
Problem 13P
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Write the MAJOR product(s) of the following reactions:
H2C
CH-
EN
+
а.
OH
H.
c=0
H3C-
CH CH-
CH EOCH-
-CH3
b. H3C
H.
Transcribed Image Text:Write the MAJOR product(s) of the following reactions: H2C CH- EN + а. OH H. c=0 H3C- CH CH- CH EOCH- -CH3 b. H3C H.
HC
C-
CH
CH3
+ disiamylborane with H2O2, "OH, H20
d.
HC
е.
-CH2
-CH3
H9SO4, H2SO4, H2O
+
HC ECH-
f.
C EN
+
H2C =CH-
-CH CH2
Transcribed Image Text:HC C- CH CH3 + disiamylborane with H2O2, "OH, H20 d. HC е. -CH2 -CH3 H9SO4, H2SO4, H2O + HC ECH- f. C EN + H2C =CH- -CH CH2
Expert Solution
Answer to a.

The reaction mentioned here is a diel Alders reaction. The reaction is a pericyclic reaction between a diene and a dienophile. The intermediates formed during the reaction are formed by movement of electrons around in a circle. 

The reaction happens in single step just by heating the reactants.   Chemistry homework question answer, step 1, image 1

 

 

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