X, R' NANH, or NaH or NaOH, A R-C=C-R' Internal alkyne (12) C=C R' H. Vinylic halide X, 1. NaNH, or NaH 2. H20 R-C CH Terminal alkyne (13) C=C R' H. Vinylic halide
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Base abstracts proton and the leaving group leaves.
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- Assuming a 56.8% yield, how kany ml of alkene is required to produce 22.5 mL of 2,3-dimethyl-2-butanol? MW of alkene: 84.16, d: 0.653 MW of 2,3-dimethy-2-butanol: 102.17, d:0.823Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):Which of the following statements best describes the stereospecificity of the resultingproduct of oxidation of an alkene using KmNO4? *Hydroxyl groups are found on opposite side.Alcohol groups undergo bond rotation.Alcohol groups are transformed into acids.Hydroxyl groups are found on the same side.What is the expected product from the hydrohalogenation of hex-1-ene using HCl? *1-chlorohexane1-chlorohex-1-ene1,2-dichlorohexane2-chlorohexane
- Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino nahWhen (CH3CH2)3CBr is added to CH3OH at room temperature, the product is(CH3O)C(CH2CH3)3. Propose a mechanism(s) for the reactions leading to theseproducts and use curved arrows to show the movement of electrons.A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactions
- How did you convert the c to k that's my only question like 25.5c to k and you got 298.65?Draw the product of the reaction of 1,2-dimethylcyclohexene with [math]H_{2}[/math] over a Pd catalyst. Show stereochemistry with wedged and dashed bonds.Solution:- 3. Determine the amount, in of a (2.20 M s olution of dichloromethane needed to completely react with 15.72g cyclohexene to give 1,2-dibromocuclohexanw. Assume 12% excess is needed in order to react completely. a . How much 1,2 -dibromocyclohexane would theoretically be produced ? c. How many ML of the 2.20 M Br2 solution are required?
- 1,2 addition of Br2 to an alkene results in a _______________. A. alcohol B. vicinyl dihalide C. alkyl halide D. geminal dihalideName the alkene below.Use only E/Z designators to indicate stereochemistry.is steric hinderance not an issue here? why when reacting with KOC(CH3)3 does it yield 2-isopropyl-1-pentene and it yields 2,3-dimethyl-2hexene here?