You know that the wavenumbers of the rotational transition J = 1← 0 for 1H 35Cl and 2H 35Cl are 20.8784 and 10.7840cm-1 , respectively. Accurate atomic masses are 1.007825 and 2.0140 for 1H and 2H, respectively. The mass of 35Cl is 34.96885. Conclude based on this information that the bond lengths are the same or different
Electronic Transitions and Spectroscopy
The term “electronic” connotes electron, and the term “transition” implies transformation. In a molecule, the electrons move from a lower to a higher energy state due to excitation. The two energy states, the ground state and the excited state are the lowest and the highest energy states, respectively. An energy change is observed with this transition, which depicts the various data related to the molecule.
Photoelectron Spectroscopy
Photoelectron spectroscopy (PES) is a part of experimental chemistry. It is a technique used in laboratories that involves projecting intense beams of radiation on a sample element. In response, the element ejects electrons for which the relative energies are measured.
You know that the wavenumbers of the rotational transition J = 1← 0 for 1H
35Cl and
2H
35Cl are 20.8784 and 10.7840cm-1
, respectively. Accurate
1.007825 and 2.0140 for 1H and 2H, respectively. The mass of 35Cl is
34.96885. Conclude based on this information that the bond lengths are the same
or different
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