You titrated phosphoric acid H3PO4 (Ka1 = 7.5×10-3, Ka2 = 6.2×10-8, Ka3 = 4.2×10-13) with a strong base and you likely expected to observe 3 equivalence points on the titration curve.  However, the titration curve does not show a sharp pH increase at the third equivalence point.  Explain why this happens.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter16: Reactions Between Acids And Bases
Section: Chapter Questions
Problem 16.64QE
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You titrated phosphoric acid H3PO4 (Ka1 = 7.5×10-3, Ka2 = 6.2×10-8, Ka3 = 4.2×10-13) with a strong base and you likely expected to observe 3 equivalence points on the titration curve.  However, the titration curve does not show a sharp pH increase at the third equivalence point.  Explain why this happens.

 

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