Photoelectron spectra were acquired from a sample ofgaseous N2 using He(I) light with energy 21.22 eV as theionization source. Photoelectrons were detected withkinetic energy values 5.63 eV and also with 4.53 eV. Calculate the ionization energy for each group of electrons.Identify the MOs that were most likely the sources ofthese two groups of electrons.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter6: Quantum Mechanics And Molecular Structure
Section: Chapter Questions
Problem 39P: The photoelectron spectrum of HBr has two main groups of peaks. The first has ionization energy...
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Photoelectron spectra were acquired from a sample of
gaseous N2 using He(I) light with energy 21.22 eV as the
ionization source. Photoelectrons were detected with
kinetic energy values 5.63 eV and also with 4.53 eV. Calculate the ionization energy for each group of electrons.
Identify the MOs that were most likely the sources of
these two groups of electrons.

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