In this experiment, the E° of three voltaic cells, and two concentration cells was calculated using a voltage probe. These E° readings were used to determine the identities of two metals, X and Y, which were used as anodes in two of the voltaic cells. The Nernst equation was then used to determine the Ecell of a copper concentration cell, and the concentration of Pb2+ in a lead concentration cell. Using the concentration of Pb2+ from the lead concentration cell, the Ksp of PbI2 was determined. The theoretical E° of the Cu-Pb voltaic cell was calculated by using the equation E°cell = E°cathode - E°anode. The cathode in part A was copper, while the anode was lead. The E° of copper, was 0.34V, and the E° of lead was -0.13V, and subtracting the E° of lead from the E° of copper resulted in the theoretical E°cell value of 0.47V. The average corrected E°cell for the Cu-Pb voltaic cell was found to be 0.492V, which is quite close to the theoretical value of 0.47V. The average corrected E°were recorded in the following table: Run Cu-Pb Pb-”X” Pb-”Y” Cu Conc. Pb Conc. 1 0.488 0.985 0.396 0.034 0.198 2 0.481 1.022 0.394 0.028 0.138 3 0.507 1.042 0.390 0.036 0.110 Average 0.492 1.0163 0.3933 0.03267 0.149 The two half-reactions for the CuPb voltaic cell were found to be: Cu2+(aq) + 2e- → Cu(s) Pb(s) → Pb2+(aq) + 2e- Net Ionic Equation: Cu2+(aq) + Pb(s) → Cu(s) + Pb2+(aq) The Cu-Pb voltaic cell can be denoted in standard cell notation as: Pb|Pb2+||Cu2+|Cu The theoretical E° of the
Due to this fact, the concentration of copper in the solution is able to be calculated by using light absorbance. Since zinc doesn’t absorb any light, we are able to deduce that the greater the absorbance, the greater the concentration of copper.
The purpose of the experiment is to cycle solid copper through a series of five reactions. At different stages of the cycle, copper was present in different forms. First reaction involves reaction between the copper and nitric acid, and copper changed from elemental state to an aqueous. The second reaction converted the aqueous Cu2+ into the solid copper (2) hydroxide. In the third reaction Cu(OH)2 decomposed into copper 2 oxide and water when heated. When solid CuO reacted with sulfuric acid, the copper returned to solution as an ion (Cu2+). The cycle of reactions was completed with the reaction where elemental copper was regenerated by Zn and Cu
One of the most important skills to have in the chemistry lab is the understanding of how chemicals will react. Knowing for example, how a chemical will react with a metal, is an excellent way of determining the amount of a particular metal in a deposit. This knowledge was used in this lab to determine the amount of copper in an unknown sample mixture. It is also known that the determination of the percent concentration of a certain solution, will directly effect the percent transmission and absorption of a solution, dependent upon its dilution. By first testing known concentrations of a solution, and plotting this information graphically, a line is formed
In Part 1 of the lab, a solar cell was created and tested for its capability to conduct electricity. After researching the processes that contribute to the conductive property, it was found that the oxidized substance is the dye, as it donates an excited electron to the titanium oxide. Consequently, titanium oxide is reduced before it donates an electron to the cathode. The electrolyte solution was found to replenish the dye with electrons so it could continue to act as a reducing agent.
Q1. In 1944, at the beginning of his book What is Life, the great physicist Erwin Schrodinger asked the following question: “How can the events in time and space which take place within the spatial boundary of a living organism be accounted for by physics and chemistry?" What would be your answer today?
The performance of the electrode depends on two important factors namely microstructure and morphology and the effect of doping. These two factors influence the type of cathode materials that can be chosen for the battery. Intercalation and deintercalation happen along particular crystallographic planes and headings, so higher crystallinity enhances terminal
2PbS + 3O2 2PbO + 2SO2 On the left side of the equation lead(II) has an ionic charge of +2, sulfur has a charge of -2, and oxygen has a charge of 0. In the reaction sulfur lost 6 electrons leaving its charge at +4. On the right side of the equation lead(II) and oxygen still has the same ionic charge and the 2SO2 is neutral because of the loss of sulfur’s electrons. 18.
A lot of information from different sources was gathered with the purpose of comparing different Li-ion batteries mechanisms, cathode and anode materials, structure and fabrication procedures, and their respective advantages and disadvantages.
The main objective of this experiment is to carry out qualitative analysis to identify metal cations in unknown solution 1.
In this lab an attempt was made to determine the concentration of a Ba(OH)2 solution by using the conductimetrically determined equivalence point of the reaction between Ba(OH)2 and H2SO4 and by gravimetric determination. The molarity using the equivalence point was determined to be 0.076 M, with a percent error of 24% (actual value was 0.100 M). The molarity using gravimetric determination was 0.0835, an error of 17%. One possible error is the presence of bubbles in the buret. Bubbles would have caused the buret reading to be too high, resulting in a larger equivalence point. Another possible error deals with the colloidal nature of barium hydroxide due to its relatively low solubility. The colloidal barium hydroxide would make it
A potential set-up was prepared wherein the 25 x 150 mm test tube was filled with K2SO4 (30mL, 0.15 mol) saturated at 0 °C in 5M H2SO4. The test tube was immersed in ice, power supply was adjusted to give the solution a current of ~3.0 amps. Current was read and recorded as accurately a possible, as well as the time over which electrolysis was carried out. K2S2O8 precipitated over a period of 45-50 minutes during which the temperature was maintained close to 0 °C (~8 °C or lower) during electrolysis.
LEARNING OBJECTIVES The learning objectives of this experiment are to. . . ! ! determine changes in enthalpy and entropy of the reaction of zinc with copper sulfate using two methods: electrochemistry and calorimetry. compare the enthalpy values obtained by the two methods. BACKGROUND Thermodynamics is concerned with energy changes that occur in chemical and physical process es. The enthalpy and entropy changes of a system undergoing such processes are interrelated by the change in free energy, ªG, according to the equation
12. The crocodile clips are attached to the copper electrodes of the experimental apparatus and the power supply is turned on. Simultaneously, the stopclock is started. The thermometer is checked every 30s. 13. After 300s the stopclock is stopped and the power supply is turned off. The negative cathode is carefully removed and is dried using a hair dryer. 14. When dry the negative cathode is placed on the electronic milligram balance and its final mass is recorded. 15. The positive anode and negative anode of the experimental apparatus are disposed and the electrolyte is poured out to ensure that the anode slime (impurities) does not contaminate the solution. 16. The electrodes of the experimental apparatus are replaced with new copper strips. 17. Steps 7 to 16 are repeated. However, this time, the rheostat is adjusted using the calibration apparatus until the multimeter shows approximate readings of 0.40 A, 0.60 A, 0.80 A and 1.00 A respectively. 18. Time permitting, the entire experiment is repeated. Safety Copper sulphate may cause irritation and burns if it comes into contact with the eyes. As standard lab procedure, safety goggles and lab coats must be worn at all times. Control of Variables Volume of Electrolyte Used
And copper (II) ions were reduced to copper because it gained electrons and its oxidation number changed from +2 in copper (II) ions to 0 in copper.
Large solar plants occupy a vast area of land and threaten wildlife because one square kilometer is needed to produce 40 megawatts of energy from solar power.4 British scientists are attempting to improve the effectiveness of photovoltaic cells by utilizing “copper indium diselenide and cadmium telluride to find an affordable and more sustainable way to make solar panels to convert light energy into electricity.”5