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Citric Acid On The Viscoelasticity Of Cornstarch

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Effects of Citric Acid on the Viscoelasticity of Cornstarch Pastes
MADOKA HIRASHIMA, RHEO TAKAHASHI,
AND

KATSUYOSHI NISHINARI*

Department of Food and Human Health Sciences, Graduate School of Human Life Science, Osaka City University, Sumiyoshi, Osaka 558-8585, Japan

The effects of citric acid on the rheological properties of cornstarch pastes were studied by steady shear and dynamic oscillatory viscoelasticity, intrinsic viscosity measurements and microscopic observation. The pH of cornstarch dispersion was adjusted between 6.0 and 3.0. The viscosity of the pastes was increased by lowering the pH (between 5.5 and 3.6), while the viscosity of samples with pH below 3.5 decreased further than that of the control (pH ) 6.3). Citric …show more content…

After stirring the dispersions at 200 rpm for 30 min at 25 °C, the cornstarch dispersions were heated to 97 °C, stirring at the same rate and maintained at 97 °C for 60 min. Then, the hot dispersions were poured into glass vessels and cooled in a water bath at 25 °C equipped with a temperature regulator, stirring with magnetic stirrers. The samples were also prepared, which were then adjusted to the pH after heating and cooling the starch dispersions (i.e., after gelatinization of starch). The final concentration of cornstarch was 3.0 wt %. Steady Shear and Dynamic Oscillatory Measurements. Steady shear and dynamic oscillatory measurements of starch pastes were carried out using a Fluids Spectrometer RFS II (Rheometrics Co. Ltd., Piscataway, NJ) with a 50-mm diameter plate geometry. The gap was adjusted to 1.00 mm. All measurements were made at 25.0 °C. From these measurements, shear viscosity (ηγ), storage modulus (G′), loss ˘ modulus (G"), and complex viscosity (|η*|ω ) (G′2 + G′′2)1/2/ω) were

Figure 2. Shear viscosity (ηγ) of 3.0 wt % cornstarch pastes as a function ˙

Figure 1. Schematic diagram of the cornstarch paste agitator. obtained. Strains for dynamic oscillatory measurements were chosen in the plateau range of each sample on the strain dependence measurements. Microscopic Observations. Microscopic observations were made using OPTIPHOTO (Nikon Co. Ltd., Tokyo, Japan) equipped with 2Dcolor CCD (1280 × 960 pixels). Unheated cornstarch dispersions and

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