How does Concentration affect the rate of reaction between Magnesium and Hydrochloric acid?
Secondary resources:
Chemical reactions only occur when reacting particles collide with each other, with sufficient energy to react, this is called the collision theory. The minimum amount of energy required to cause this reaction is called the Activation energy. There are four main factors which affect the rate of reaction. The first factor is:
Temperature of reactants:
When the temperature increases the particles move around faster
(because they have more energy). Because the particles are moving faster , they are more likely to collide. When the temperature is low, the particles are slower and they also collide less. The
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If there is a smaller surface area there is less collisions, therefore there is a decrease in the rate of reaction.
Aim:
My aim for carrying out this investigation is to find out whether concentration effects the rate of reaction between Hydrochloric acid and magnesium metal.
Mg+2HCL ---- MgCl +H
Magnesium +hydrochloric acid ---- Magnesium chloride +hydrogen
Pre-test:
I have decided to use the water displacement method to collect the gas. While carrying out my pre-test, I performed experiments with different amounts, times, lengths etc in order to establish the most appropriate quantity.
I have decided to use magnesium granules instead of magnesium strips and magnesium powder because when I experimented with magnesium strip
It took way to long for the gas to be collected. When I experimented with magnesium powder the gas was collected to fast. So I decided to use magnesium granules because the time of the gas to be collected. As you can see the results below match my statement.
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Magnesium (g) HCA (cm) H20 (cm) Time (s)
0.1g (granules) 20cm 0 12.38
0.1g (strip) 20cm 0 26.70
0.1g (powder) 20cm 0 No time
During the immersion of the magnesium metal in the hydrochloric acid solution, white bubbles could be seen escaping the surface of the metal as gas was produced during the reaction. Depending on the temperature of the hydrochloric acid and the overall molar concentration, the rate of reaction differed but the same signs were shown. During the reaction between the magnesium metal and higher concentrations of hydrochloric acid, it was observed that the test tube grew quite warm to the touch. As the immersed magnesium strip sank down, it appeared coated in a layer of white bubbles that fizzed like a carbonated drink. In the lower concentrations of hydrochloric acid, the strip spent some time floating at the surface of the solution in the test tube, later sinking down to the bottom as the
If the concentration of the solution is increased the particles have less room to move around which creates a greater chance of collisions. The surface area of the reactant greatly affects the speed of which it reacts because if the reactant is grinded up or cut up the solution has more room to get to it. The reaction rate can be calculated by the formulae; rate of reaction = total amount of reactant used or product made ÷ time taken. (Collision theory and rates of reaction, 2013)
How concentration affects the rate of reaction between Hydrochloric Acid and Sodium Thiosulphate Chemistry Coursework How Concentration Affects a Reaction Aim: The aim of this experiment is to find out how concentration affects the rate of reaction between Hydrochloric Acid and Sodium Thiosulphate. Introduction: This experiment will be carried out by drawing a cross on a piece of paper and mixing hydrochloric acid and sodium thiosulphate together to see if the cross disappears. The concentration of hydrochloric acid would change every reaction to show that concentration effects a reaction.
In this lab, a calorimeter was used to find the enthalpy of reaction for two reactions, the first was between magnesium and 1 molar hydrochloric acid, and the second was between magnesium oxide and 1 molar hydrochloric acid. After the enthalpy for both of these were found, Hess’ law was used to find the molar enthalpy of combustion of magnesium, using the enthalpies for the two previous reactions and the enthalpy of formation for water. The enthalpy of reaction for the magnesium + hydrochloric acid reaction was found to be -812.76 kJ. The enthalpy of reaction for the magnesium oxide + hydrochloric acid reaction was found to be -111.06 kJ. These two enthalpies and the enthalpy of formation for water were manipulated and added together using Hess’s law to get the molar enthalpy of combustion of magnesium. It was found that the molar enthalpy of combustion of magnesium was -987.5 kJ/mol. The accepted enthalpy was -601.6 kJ/mol, which means that there is a percent difference of 64%. This percent difference is very high which indicates that this type of experiment is very inefficient for finding the molar enthalpy of combustion of magnesium. Most likely, a there are many errors in this simple calorimeter experiment that make it inefficient for finding the molar enthalpy of combustion of magnesium.
Many factors effect reaction rates, two shown above include temperature and concentration. Concentration affects the rate of reactions because the more concentrated a solution the more likely collisions between particles will be. This is simply because there are more particles present to collide with each other. When the temperature is higher, particles will
This image explains that the higher the temperature, the concentration, and the pressure the faster the rate of the reaction is.
Magnesium will react with hydrochloric acid, because it is higher in the reactivity series than hydrogen. The magnesium displaces the hydrogen in the acid, so it forms magnesium chloride and hydrogen gas.
There was an increasing trend because the metal was the limiting reactant in this experiment. The amount of each metal placed in the hydrochloric acid was fully used up before the acid was. From Figure 1, it is clear that aluminum produced the most amount of hydrogen gas, then magnesium in the middle and zinc produced the least amount of hydrogen gas. This shows that the same mass of each metal does not produce the same amount of hydrogen gas. Looking at the balanced equations for each of the metals (see lab 2-1, equation 1 and 2), it seems the metals have a similar stoichiometry, however zinc produced a lesser amount of hydrogen gas compared to magnesium because zinc has a higher molar mass than magnesium does. Due to this, more zinc is needed to produce the same amount of hydrogen gas as magnesium. When aluminum and magnesium are compared, it is seen that aluminum and magnesium have similar molar masses, however they have a different stoichiometry (experiment 2-1, equation 1 and 3). Two moles of aluminum react to produce three moles of hydrogen gas, while one mole of magnesium react to produce one mole of hydrogen gas. Based on this stoichiometry, a higher mass of magnesium is needed to produce the same amount of hydrogen gas as
The term concentration refers to the amount of a substance present in a certain volume of liquid or gas. Increasing the concentration of the reactants will increase the rate of the reaction. If the concentration of a reactant in a solution is increased, there will be a greater number of particles in a given volume of solution. This means the particles are more likely to collide and therefore react when there are more of them. Collisions between particles are necessary for the reactants to rearrange and form the products. In this experiment, the rate of the reaction between magnesium ribbon and hydrochloric acid will be increased by adding a higher concentration of hydrochloric acid each time. The chemical equation between magnesium ribbon and hydrochloric acid can be written as:
Hypothesis: If the concentration of a substrate increases, any time an enzyme happens upon a substrate it will be free to help that substrate react, but then when an enzyme encounters a new substrate at a slightly higher concentration it will already be working on another substrate, therefore, as we increase substrate concentration it is not going to increase as fast as the reaction rate.
Science Coursework – What factors effect the rate of reaction between magnesium and hydrochloric acid? Background Knowledge There are four factors that can affect the rate of reaction and they all rely on the collision theory. This is basically how hard and how often particles collide with each other. The more and harder they collide, the faster the reaction time will be.
Overall, the results were almost as expected. It was predicted that Magnesium and Calcium would have a similar reaction will the hydrochloric acid and produce approximately that same quantity of hydrogen gas. However, the results demonstrated that the Calcium reacted more vigorously than expected and produced a larger quantity of hydrogen gas. The reaction which occurred whilst using Magnesium resulted exactly like the prediction. It was expected that the metal would bubble, eventually dissolve and produce gas which would potentially displace the water in the test tube. With the reaction involving Calcium, it was not predicted that it would heat up the conical flask and react as violently. It was expected that the Tin would either have a
was too fast to measure and so for my scale to reach above that, I
This has a high chance of chemical reaction, as there is little space to move without colliding with another particle. This causes the high chance of collision and chemical reaction, and shows that the higher the concentration, the more chemical reactions will take place. Collision Theory = ==
Experiment to investigate factors affecting the rate of reaction between magnesium ribbon and hydrochloric acid