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Lab Report On The Laboratory

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The laboratory consists of (1) an introductory tutorial on electrochemistry that introduces several electrochemical techniques used in research laboratories and (2) an analysis section that implements these techniques to characterize water electrolysis half reactions. A flow chart outlining the laboratory is shown in Scheme 2. The laboratory is carried out in groups of two to three students in a 4-hour lab period and discussion questions and calculations are assigned with the laboratory write up. The laboratory typically takes 3 hours, which allows students time to begin work on the post-laboratory assignment. This laboratory was performed several times and pre- and post-lab surveys indicated that students successfully engaged the …show more content…

The fitted Tafel plot analysis produces an experimental value for i0, which is compared to the value obtained from CV simulation parameters, providing a link between experiment and theory.
In the second section of the laboratory, students apply the electrochemical techniques introduced in the tutorial portion to examine water splitting. First, water reduction
2H^+ (aq)+2e^- H_2 (g) is carried out with a gold electrode and then with a platinum working electrode. Platinum itself is a catalyst for hydrogen production. Thus, the CV taken with the platinum electrode reveals features of catalysis, which are detailed in the discussion section. Second, for analysis of water oxidation,
2H_2 O(l) 〖4H〗^+ (aq)+O_2 (g)+4e^- students electrochemically synthesize a cobalt-phosphate water oxidation catalyst on an FTO-coated glass slide electrode. They evaluate the performance of catalyst compared to the bare FTO-coated slide. A Tafel analysis is performed on the water oxidation catalyst.
Hazards
K3[Fe(III)(CN)6] , Na4[(Fe(II)(CN)6] and Co(II)(NO3)2 are harmful if swallowed and cause irritation to the eyes and skin. Cobalt nitrate is an oxidizer and must be stored separately from other materials.
Calculations, Results and Discussion
Electrochemistry Tutorial: One-electron Reduction of Potassium Ferricyanide: Figure 1 shows typical CV and DPV scans of the ferricyanide/ferrocyanide solution with the platinum and glassy carbon working electrodes. Two working

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