0 A certain half-reaction has a standard reduction potential Ered = +0.60 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 0.50 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. ロ→ロ 0 yes, there is a minimum. E = red Πν no minimum 0 ○ yes, there is a maximum. E = red Ον By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used at the anode of this cell. ☐ Note: write the half reaction as it would actually occur at the anode. no maximum ☑

0 A certain half-reaction has a standard reduction potential Ered = +0.60 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 0.50 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. ロ→ロ 0 yes, there is a minimum. E = red Πν no minimum 0 ○ yes, there is a maximum. E = red Ον By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used at the anode of this cell. ☐ Note: write the half reaction as it would actually occur at the anode. no maximum ☑

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter17: Electrochemistry

Section: Chapter Questions

Problem 160MP

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Similar questions

The half-cells Ag+(aq. 1.0 M)|Ag(s) and H+(aq, ? M)|H2(1.0 bar) are linked by a salt bridge to create a voltaic cell. With the silver electrode as the cathode, a value of 0.902 V is recorded tor kcell at 298 K. Determine the concentration of H+ and the pH of the solution.
a Calculate G for the following cell reaction: Tl(s)Tl+(aq)Pb2+(aq)Pb(s) The Gf for Tl+(aq) is 32.4 kJ/mol. b From G, calculate the standard cell potential for the cell reaction and from this, determine the standard potential for Tl2+(aq)+eTl(s).
At 298 K, the solubility product constant for solid Ba(IO3)2 is 1.5 109. Use the standard reduction potential of Ba2+(aq) to find the standard potential for the half-reaction Ba(IO3)2(s)+2eBa(s)+2IO3(aq)
Halide ions can he deposited at a silver anode, the reaction being Ag(s) + X- AgX(s) +e- Suppose that a cell was formed by immersing a silver anode in an analyte solution that was 0.0250 M Cl-,Br-, and I -ions and connecting the half-cell to a saturated calomel cathode via a salt bridge. (a) Which halide would form first and at what potential? Is the cell galvanic or electrolytic? (b) Could I- and Br- be separated quantitatively? (Take 1.00 l0-5 M as the criterion for quantitative removal of an ion.) If a separation is feasible, what range of cell potential could he used? (c) Repeat part (b) for I- and Cl-. (d) Repeat part (b) for Br- and Cl-.
Consider a galvanic cell based on the following half-reactions: a. What is the expected cell potential with all components in their standard states? b. What is the oxidizing agent in the overall cell reaction? c. What substances make up the anode compartment? d. In the standard cell, in which direction do the electrons flow? e. How many electrons are transferred per unit of cell reaction? f. If this cell is set up at 25C with [Fe2+] = 2.00 104 M and [La3+] = 3.00 103 M, what is the expected cell potential?
A half-cell that consists of a copper wire in a 1.00 M Cu(NO3)2 solution is connected by a salt bridge to a solution that is 1.00 M in both Pu3+ and Pu4+, and contains an inert metal electrode. The voltage of the cell is 0.642 V, with the copper as the negative electrode. (a) Write the half-reactions and the overall equation for the spontaneous chemical reaction. (b) Use the standard potential of the copper half-reaction, with the voltage of the cell, to calculate the standard reduction potential for the plutonium half-reaction.
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Consider a galvanic cell for which the anode reaction is 3 Pb(s)Pb2+(1.0102M)+2e and the cathode reaction is VO2+(0.10M)+2H3O+(0.10M)+eV3+(1.0105M)+3H2O(l) The measured cell potential is 0.640 V. Calculate E for the VO2+V3+ half-reaction, usingE(Pb2+Pb) from Appendix E. Calculate the equilibrium constant (K) at 25°C for thereaction Pb(s)+2VO2+(aq)+4H3O+(aq)Pb2+(aq)+2V3+(aq)+6H2O(l)