Q: CH3 За. ВНз. ТHF Et20, EtOH B2 B1 зь. NaOH, H202 "CHз 2. Н, саt. (PҺ3P);RhCI toluene A) (a) and (b)…
A: Birch reduction is the reduction of arenes to cyclo Hexa dienes, in the presence of sodium in liquid…
Q: -OCH3 d. CH;CHCH,CH3 а. ÓH CH3 OH b. CH3OCCH3 CH3 с. CH-CH,0CHCH-CH; f. CH;CH,CHCH;CH,CH3 CH3 ОН
A: Ether can be synthesized from alkene by oxymercuration-demercuration reaction.
Q: ОН О || CH3-CH-C-OH d. H2N-CH2-C-OH е. CH3 H3C. C-H ČH3 f.
A:
Q: 9. NAHSO: CH: - C- CH3 19). 10. L(10a) + + NaOH HC-O-Na + _(10b)_
A: Acetone reacts with sodium bisulphite to form acetone bisulfitethis is addition reaction.
Q: Rank the water solubility of the following compounds:
A: Given compounds,
Q: Draw the products in each reaction.
A: NOTE: Since, we only answer upto three sub-parts, we'll answer the first 3. Please resubmit the…
Q: С. Br d. -Ċ–CI CH, —CH—CH,—С—Вr CI е. f. g. CH;-C-F CH;-CH,-C–CI
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Q: Give an acceptable name for each amine.
A: Amines are the chemical compounds which consists a nitrogen atom that is attached to aliphatic…
Q: CH3 CH,CH2-C-CH,CH2 f. CH3 CH3 CH,CH,CH2-C-CH3 ČH3
A:
Q: nplete tihe reactio H20 HC=CH H*, Hg2+ Cu propanol 250 °C KMNO4 C=C-CH3 нн H*/ t°C NABH4 H3c-C…
A: The detail solution for this reactions is provided below in attach image.
Q: 1. 2. 3. 4. 5. HC1 + CH3I -CH3 + HONO N-H + a N- -H NHCH3 + HONO
A: Here we have to write the major product formed in the following given reactions.
Q: COCI CH;NH,. b. CO2CH2CH3 1. CH;CH;MgBr 2. Hy0* с. CH;OH H2SO4 - CH3
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Q: 1. Hg(OAc)2, H2O 2. NaBH4 CH2OH HO -HO- I| OH II IV
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Q: 1) HO 2) CH3CH2CH2C1 AICI3 CI NaOH, 100 °C ? CH3 H3CT CH3 Ph C Br ? CH3 t-BUOH
A: The following reactions has to be completed
Q: He SO4 H3C. H HọC CH; CHz GH CHo > = C メ + C=C +H20 CH3 trals-2-buten cis-2-buter 23%
A: Saytzeff’s Rule stated that stable alkene is formed when the removal of hydrogen from β-carbon has a…
Q: 1) ? HO 2) CH3 CH2CH2C1 AICI3 CI- NaOH, 100 °C ? CH3 CH3 Ph H3C. Br ок O K* CH3 t-BUOH
A: Hey since you have posted a question with multiple sub-parts, we will solve first three sub-parts…
Q: d. (d) CH;CH2CH2CH,CH(OH)OCH3 е. (е) CH;CH,CH,CH,CH(OCH3)2 f. (f) HO,
A: Tollen's test is used to distinguish aldehyde functional group from the other functional groups in…
Q: The instructions are to draw the molecule oriented as : Br going towards me while OH is going away…
A: The compound CH3CH(Br)CH(OH)CH3 drawn as
Q: Grive the meckamiem of given जप्बत्जेनक र i) H2NNH2 2) KOH dCH 3 HI B HCN H30 B (10)
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Q: 4. CHg CH2-NH- CH2 CHz 5. CH, CH2 CH2 CH2-Ċ-0H
A: Organic compounds can be defined as the compounds containing carbon and hydrogen atoms. For example,…
Q: O C5 H12 CH3-NH, ⒸHO-CH₂-CH(CH3)-OH O C₂H3 CN
A: Answer - The correct option is (c) HO-CH2-CH(CH3)-OH Explanation - According to the question -…
Q: CH3-CH2-CH2-NH3* CI + NaOH etq CH3 ow or mi en CI CH3- N*-H КОН + CH3
A: In the reactions given, there is a ammonium salt of which is a weak acid which is reacting with…
Q: CH,-C-0-CH, + Figure 39 t (s) II CH-C-CI + A CH-NH2 CH-C-NH-CH, + HCI H* B CH-C-OH + CH-OH H20 он CI…
A: A nucleophile is a nucleus loving species. An electrophile is an electron loving species. A good…
Q: I 2 345 CH3CFCH,CH,CH,CH3 - Pent are е. CH2CHECH u-C-c-GーC-C~) A-C-H C-H=C-H CI f. H. CH3 エ エ エ
A: The first and the foremost step while naming the IUPAC name of an organic compound is the…
Q: H2NNH2, ОH (d) CH3-CH2-C-CH2-CH3 1. LIAIH4 (u) 2. Hзо* H2NNH2, OH (w) Нeat
A: In presence of NH2NH2 / OH- Aldehyde and ketones undergo Wolff Kishner reduction and we get Alkane…
Q: Draw the products of each reaction.
A: Since your question has multiple subparts, we are solving only first three subparts for you. If you…
Q: C12 /light Br2/light Na/Ether (i) CH3CH3 C P205 Cr207/ H* В 03/Zn/H2O (ii) CH3CH2CH(OH)CH3 А C
A: In a chemical reaction; the substance which involves in conversion is said to be reactant whereas…
Q: (iv) [(n²-C;H3)(n°-CHs)M(CO)]"
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Q: ¹) O || CH2-CH₂-CH₂-CH₂-C-H b) O CN: || CH3-CH2-CH2-CH2-CH2- C -CH2-CH2-CH2-CH3
A:
Q: CI excess CH2CH,CI 1. KMNO/NAOH/H;O 2. H3O* AICI3 AICI3 OH Он OH OH OH I3D II IV OAR OB.V
A: The series of reactions is as follows:
Q: (g) (e) -OH-CH=CH-_1_C1₂ CH₂-C OH CH₂ CH₂ HCUN O Heat KMnO4, hot H* 1. NaBH4 2. H₂O
A:
Q: 1. CH3 1 H3C-CH-O-CH₂CH3 HỌC CHỊCH, 2. CHOO + + H-Br: CH₂=CH-C=CH₂ 3 CH3 1 - H3C-CH-O-CH₂CH3 + H :…
A:
Q: hamess CH3-CH cH3- cH3 -CH cH3-CH cH
A: In IUPAC nomenclature of ether the most complex group is named as alkane as root word where as the…
Q: name of the #. f) CH, CH=CHCH-CH3 I. Give he IUPAC a) CHz- CA - CH CH. Br 6) CH; - CH - CH - CH, CH,…
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Q: Name the following compounds: 1. 2. Br Hc-CH-CH-ö-OH 3. -CH-CH 4. H,C-CH-CH-OH CI 5. HC-C=C-CH,-CH,…
A: According to our policy we should solve one question (If any subparts present then we should solve…
Q: Provide the starting materials needed to prepare the following compounds:
A: Aldol condensation:- It is defined as the condensation reaction where generation of enolate ion…
Q: PHCOOCH2CH(CH3)2 CHACONHCH,PЬ (CH)2СHCOOCНО -0-C- Н СООН H CN COCI Br
A: Since you have posted a question with multiple sub-parts, we will solve the first three sub-parts…
Q: (d) (e) (f) H-CEO- CH3CH₂MgBr H₂O, H₂SO4 HgSO4 1.03 2. H+, Zn
A:
Q: IBc. B H-C-C-H Br Br OOH 2. 2 KMNO + 3 H-C-CH- CHi± 2KOH + 3. CH:CH-CH-CH: + 4H:O +2MNO2 HC CH-…
A:
Q: For each of the reactions indicate which reactant is the nucleophile and which is the electrophile.
A: Since your question has multiple sub parts, we are solving only first three sub parts for you .If…
Q: 1+ 25. CH2=CH2 + CH3COOH ????? - A) CH3-CH2-Ċ-CH3 B) CH3-CH,-O-C-CH3 C) CH3-CH2-OH + CH3-C=0 D)…
A: This reaction type is called synthesis. Synthesis is when two or more compounds which combine or…
Q: CH,-CH=CH, | hv (i) –CH3 CH3
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Q: 1) NaBH4 2) CH,CH,ОH OCH2CH3 (А) (В) CH2OH OCH,CH3 ОН (С) ОН (D) .CH2OH OCH2CH3
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Q: 1. Hg COAC)2 , M20 HO a) 2. NaBHly, NAOM major product b) 1) O3 2) (CH3)2S C10H18
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Q: CH-CH,-CH, (6) (5) CH, CHy-C CH2-CH2-CH2-CH3 CH3 (7)
A: " Since you have posted a question with multiple sub-parts , we will solve first three sub-parts for…
Q: CH3 CH3 CH3 NaOCH3 H CH,0CH CH3 CH;0 CH2CH3 CH2CH3 Br SN2 H VWX XWV O VWX O XwV
A: The SN2 reaction is a nucleophilic substitution reaction. It is a one-step reaction where the…
Q: 1. 2. CH-CI 12- - --> OH XI OCH3
A: " Since you have posted a question with multiple sub-parts, we will solve first three sub-parts for…
Q: 1. Name the following compounds: а. CH3 ÇH3 .CH .CH CH2 CH3 b. HO-CH2 он CH2-CEC-CH, С. он HC SCH CH…
A: For naming of alkene and alkyne double bonded carbon are taken into longest chain and numbering is…
Q: 4. 5. 6. 7. Ст CH2CH3 OH OH H₂PO4 heat NO₂ OH PCC CH₂Cl₂ conc. HNO3.
A: Here we have to write the major product formed in the following given reactions. The major product…
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- Assign the IR spectra given in Questions 1 - 3 to their corresponding structures from the ones below. The number in parentheses next to each possible answer corresponds to the structure's Chemical Abstracts Services (CAS) number. 1-bromobutane (109-65-9) 1-cyclopropylethan-1-one (765-43-5) 1-ethyl-3-methylbenzene (620-14-4) 1,2-dimethoxynenzene (91-16-7) 2,3-dimethylbutan-2-ol (594-60-5) 3-methylbutan-1-ol (123-51-3) 3,3-dimethylbutan-2-one (75-97-8) 4-benzylpiperidine (31252-42-3) 4-methoxybenzaldehyde (123-11-5) acetic anhydride (108-24-7) acetonitrile (75-05-8) acetyl chloride (75-36-5) anisole (100-66-3) benzaldehyde (100-52-7) benzoic acid (65-85-0) benzophenone (119-61-9) benzyl acetate (140-11-4) bromobenzene (108-86-1) cyclohex-2-en-1-one (930-68-7) cyclohexanone (108-94-1) cyclopent-2-en-1-one (930-30-3) diethylamine (109-89-7) dimethyl malonate (108-59-8) ethyl 2-cyanoacetate (105-56-6) ethynylbenzene (536-74-3) heptanoic acid…For each set of spectral data below, draw the skeletal structure of the molecule that is consistent with the data. a. C5H12OMajor IR peaks: 3000 -2850 cm-11H NMR: 1.10 ppm (doublet); 3.60 ppm (septet), 3.8 ppm (quartet), 1.05 ppm (triplet) b. C3H6Br2Major IR peaks: 3000 -2850 cm-11H NMR: 2.4 ppm (quintet) and 3.5 ppm (triplet)Analyze the IR for the molecular formula C8H8O3 (vanillin). List only the relevant absorbancies (it is not necessary to list anything in the fingerprint region), descriptions (s, m, w, br), and assignments (O-H, alkane C-H, etc.).
- On spectra 1 are the mass, IR and 13 C and 1 H NMRspectra of an organic compound.1) a) From these spectra, determine the structure of the molecule.Remember to ignore the triad in the 13 C NMR spectrum at 77 ppm thatcomes from the NMR solvent. b) Draw the structure of the molecule and label each hydrogen with a letter(A, B, C...). Then fill in the peak assignment table below. hydrogen chemical shift integration splitting pattern couples toI need help with questions please show on charts, please information Functional group- primary amine Derivatives - Benzamide unknown compound C3H9N 1: Label identifiable absorption above 1400 cm-1, sp2 carbon stretch foralkenes and aromatic, sp3 carbon-hydrogen stretch, sp2 carbon-hydrogenstretch, carbon hydrogen stretches of aldehyde, O-H stretch for alcohols, andcarboxylic acid, C=O stretches, N-H for amines.2- 1HNMR: Draw the structure neatly on the spectrum with each of the hydrogenclearly labelled. Identify which signal is associated with each type of H asmuch as possible.3- 13CNMR: Draw the structure neatly on the spectrum with each of the carbonclearly labelled. Identify which signal is associated with each type of carbonas much as possibleHere are proton NMR data for 1-bromopropane: Ha : triplet (2H) 3.32ppm; Hb : multiplet (2H)1.81ppm; Hc : triplet (3H) 0.93ppm. (Relative integrations shown in parentheses.) a. Through how many bonds can a hydrogen split another hydrogen? b. According to this splitting rule, does Ha split Hc ? c. Is your answer in part a) consistent with the multiplicity listed for peak clusters a and c? d. How many hydrogenssplit Hb ? e. Upon very close inspection of the proton NMR spectrum of 1-bromopropane, you wouldfind that peak cluster b has at least six peaks. Is this consistent with your answer in part d)? f. Speculate as to why any peak cluster with more than four peaks is listed simply as a"multiplet."
- The hormone cortisone contains C, H, and O, and shows a molecular ion at M+=360.1937 by high-resolution mass spectrometry. What is the molecular formula of cortisone? (The degree of unsaturation for cortisone is 8.)Following are infrared spectra of nonane and 1-hexanol. Assign each compound its correct spectrum.For the following compound: C3H5BrO2 (Molecular Weight = 152) -Calculate the degrees of unsaturation -Use the IR and NMR to determine the structure for your compound -All 1H NMR peaks (number of signals, chemical shift, integration and splitting)-All 13C NMR peaks (number of signals and chemical shift)-All IR peaks that are important (no need to look into the fingerprint region!)-Your proposed structure of the compound (C3H5BrO2) and how it matches with the spectra (images attached)
- N-propylbenzene, C6H5CH2CH3, contains C (sp3) -H and C (sp2) -H bonds. Its IR spectrum shows strong or medium absorptions at 3085, 3064, 3028, 2960, 2931 and 2873 cm ^ -1, as well as bands below 1600cm -1. Which statement is wrong? A.) Stretching of the C (sp3) -H bonds results in absorptions at lower wave numbers than the stretching of the C (sp2) -H bonds. B.) The absorptions at 2960, 2931 and 2873 cm ^ -1 are assigned to stretching of the C (sp3) -H bonds. C.) The absorptions at 3085, 3064 and 3028 cm ^ -1they are assigned to stretching of the C (sp2) -H bonds. D.) Each absorption can be assigned to the stretch mode of a particular bond in the propylbenzene molecule.Ethers are not easily differentiated by their infrared spectra, but they tend to form predictable fragments in the mass spectrum. The following compounds give similar butdistinctive mass spectra.O Obutyl propyl ether butyl isopropyl etherBoth compounds give prominent peaks at m>z 116, 73, 57, and 43. But one compoundgives a distinctive strong peak at 87, and the other compound gives a strong peak at 101.Determine which compound gives the peak at 87 and which one gives the peak at 101.Propose fragmentations to account for the ions at m>z 116, 101, 87, and 73.For each compound shown below,(1) sketch the 13C NMR spectrum (totally decoupled, with a singlet for each type of carbon), showing approximatechemical shifts.(2) show the multiplicity expected for each signal in the off-resonance-decoupled spectrum.(3) sketch the spectra expected using the DEPT-90 and DEPT-135 techniques. H2C CH CH2Cl3-chloropropene