1. (a) Write the full balanced chemical equation for the reaction between acetic acid and sodium hydroxide. (b) A titration of 50.00 mL of acetic acid required 28.32 mL of 0.1014 M NaOH for complete neutralization. Calculate the molarity (moles/L) of the acetic acid (Ma). [Hint: see eqn top p. 41] Show work & use proper sig figs !
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- If one mixes 50cm³ of EtOH and 50cm³ of H2O at room temperature; will the total volume of the solution be 100.0 cm³? Justify answer with appropriate calculations and explanationsTo analyze an aspirin sample, 0.3470 g of crushed tablets are weighed and treated with 50.00 mL 0.1155 M sodium hydroxide, boiling for 10 minutes. Under these conditions the acid acetylsalicylic (MW, 180) reacts according to: CH3COO-C6H4-COOH + 2 OH- → OH-C6H4-COO- + CH3COO- The excess NaOH is then titrated with 11.5 mL of 0.2100 M HCl. What is the purity of said show ?.Over time, as their free fatty acid (FFA) content increases,edible fats and oils become rancid. To measure rancidity, the fator oil is dissolved in ethanol, and any FFA present is titrated withKOH dissolved in ethanol. In a series of tests on olive oil, a stocksolution of 0.050 Methanolic KOH was prepared at 25C, storedat 0C, and then placed in a 100-mL buret to titrate any oleic acid[CH₃(CH₂)₇CH=CH(CH₂)₇COOH] present in the oil. Each offour 10.00-g samples of oil took several minutes to titrate: thefirst required 19.60 mL, the second 19.80 mL, and the third and fourth 20.00 mL of the ethanolic KOH.(a) What is the apparent acidity of each sample, in terms of mass% of oleic acid? (Note:As the ethanolic KOH warms in the bu-ret, its volume increases by a factor of 0.00104/C.)(b) Is the variation in acidity a random or systematic error? Ex-plain.(c) What is the actual acidity? How would you demonstrate this?
- please help me The aluminum in a 1.200g sample of impure ammonium aluminum sulfate was precipitatedwith aqueous ammonia as the hydrous Al2O3 · XH2O. The precipitate was filtered and ignitedat 100°C to give anhydrous Al2O3, which weighed 0.2001 g. Express the result of this analysisin terms of % Al.Oxalic acid dihydrate (H2C2O4 • 2H2O, molecular weight = 126.07 g/mol), a diprotic acid, can also be used to standardize NaOH solution. If 0.284 g of H2C2O4 • 2H2O is dissolved in water and titrated to the equivalence point with 16.37 mL of NaOH, what is the molarity of the NaOH solution?1.00 grams of table salt was dissolved in 100 mL water and excess AgNO3 reagent was added and yielded 2.3789 grams of precipitate. Calculate the percentage of NaCl in the table salt. Answer must be in 2 significant figures.
- The organic base, tris-(hydroxymethyl)aminomethane (or simply TRIS or THAM) is an excellent primary standard. A 0.2486 g sample of the primary standard grad TRIS, (CH2OH)3CNH2 (M.M. = 121.14) was dissolved in distilled water and required 24.88 mL of a hydrochloric acid solution. Calculate the molarity of the solutionA 10.00 mL aliquot of vinegar (acetic acid, CH3COOH - 60.08 g/mol) was diluted in a 100.00 mL volumetric flask and made up with distilled water. An aliquot of 10.00 ml was pipetted into an erlenmeyer flask, to which two drops of phenolphthalein were added. This solution was then titrated with 0.1006 mol/L NaOH. i) Considering that the volume of NaOH consumed was 8.28 mL, what is the molar concentration of acid in dilute solution? ii) What is the acidity percentage of vinegar? iii) Whereas the expected concentration of the acetic acid solution was equal to 0.0830 mol/L, calculate the volume of NaOH needed to reach the point of equivalence. iv) Based on the volume calculated in the previous item and the volume indicated in item (i), calculate the titration error.A quantitative analysis for ethanol, C2H6O, can be accomplished by a redox back titration.Ethanol is oxidized to acetic acid, C2H4O2, using excess dichromate, Cr2O72–, which is reduced toCr3+. The excess dichromate is titrated with Fe2+, giving Cr3+ and Fe3+ as products. In a typicalanalysis, a 5.00-mL sample of a brandy is diluted to 500 mL in a volumetric flask. A 10.00-mLsample is taken and the ethanol is removed by distillation and collected in 50.00 mL of anacidified solution of 0.0200 M K2Cr2O7. A back titration of the unreacted Cr2O72–requires 21.48mL of 0.1014 M Fe2+. Calculate the %w/v ethanol in the brandy
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