1. Ferric Chloride Test Add 5 drops of FeCl3 solution to 4 different test tubes containing 1 mL each of dilute solutions of the following compounds and note the color obtained. a. Phenol _______________________________________________________________ b. Salicyclic acid ___________________________________________________________ c. Resorcinol _______________________________________________________________ d. Picric acid _______________________________________________________________ 2. Millon’s Test Prepare another set of 4 test tubes containing 1 mL each of the solutions listed below. Add 3 drops of Millon’s reagent to each and place all the test tubes in a boiling water bath. Note the color formed. a. Phenol _______________________________________________________________ b. Salicylic acid ___________________________________________________________ c. Resorcinol _______________________________________________________________ d. Picric acid ____________________________________________________

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter9: Aqueous Solutions And Chemical Equilibria
Section: Chapter Questions
Problem 9.20QAP
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E. TESTS FOR PHENOLIC COMPOUNDS
Phenolic compounds such as phenol, salicylic acid, etc., give characteristic
colors with FeCl3 and Millon’s Reagent.
1. Ferric Chloride Test
Add 5 drops of FeCl3 solution to 4 different test tubes containing 1 mL each of
dilute solutions of the following compounds and note the color obtained.
a. Phenol _______________________________________________________________
b. Salicyclic acid ___________________________________________________________
c. Resorcinol _______________________________________________________________
d. Picric acid _______________________________________________________________
2. Millon’s Test
Prepare another set of 4 test tubes containing 1 mL each of the solutions listed
below. Add 3 drops of Millon’s reagent to each and place all the test tubes in a
boiling water bath. Note the color formed.
a. Phenol _______________________________________________________________
b. Salicylic acid ___________________________________________________________
c. Resorcinol _______________________________________________________________
d. Picric acid _______________________________________________________________

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