1. Identify whether the following sets of acids and bases can function as a buffer solution. If the set can not be a buffer explain why. a. H2AsO4 and AsO43- b. H2O and Ca(OH)2 c. H2Se and KSeH d. HBrO2 and NaBrO3

Chemistry: An Atoms First Approach
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Chapter14: Acid- Base Equilibria
Section: Chapter Questions
Problem 97AE: A student intends to titrate a solution of a weak monoprotic acid with a sodium hydroxide solution...
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1. Identify whether the following sets of acids and bases can function as a buffer solution. If the set can not be a buffer explain why.
a. H2AsO4 and AsO43-
b. H2O and Ca(OH)2
c. H2Se and KSeH
d. HBrO2 and NaBrO3
2. A buffer was prepared by adding 12.00 g of Acetic acid, CH3COOH and 14.50 g of sodium acetate, CH3COONa to 250 mL of water. Ka = 1.8 x 10-5
a. Determine the pH of the buffer.
b. Determine the pH of the buffer after 16.50 mL of 2.00 M KOH was added
3. What mass of sodium benzoate, C6H5COONa should you add to 150 mL of a 0.15 M benzoic acid solution to obtain a buffer with a pH of 4.25? Ka = 6.5 x 10-5
4. Consider the titration of a 25.0 mL sample of 0.115 M RbOH with 0.225 M HCl.
a. Determine the initial pH of the RbOH solution.
b. Determine the milliliters of HCl needed to reach the equivalence point.
5. Determine the pH of a solution after mixing 60.0 mL of 0.250 M CH3COOH with 55.0 mL of 0.375 MKOH.Ka =1.8x10-5
6. Determine the pH of a solution after mixing 25.0 mL of 0.300 M CH3NH2 with 25.0 mL of 0.200 M HBr. Kb = 4.4 x 10-4
7. Determine the pH at the equivalence point when 20.0 mL of 0.606 M HBrO2 is mixed with 0.255 M NaOH. Ka = 1.2 x 10-5

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