1. Rank the stability of the carbon radicals below from least stable to most stable. В

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.21P
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Organic chemistry Help on 1 & 2

Explain the structure, geometry, and relative stability of carbon radicals.
Rank the relative C-H bond strengths within a molecule.
Draw resonance structures for carbon radicals.
Identify common curved-arrow patterns in radical mechanisms and draw mechanisms for radical
reactions using fishhook arrow-pushing patterns.
Identify initiation and propagation steps for a radical reaction.
Carbon Radical Stability & C-H Bond Dissociation Energy
1. Rank the stability of the carbon radicals below from least stable to most stable.
A
2. Within each molecule below, rank the C-H bonds indicated from weakest to strongest.
The weaker the bond, the more stable the radical formed upon homolytic cleavage.
HA
Hc
Hg
HA
HB
Resonance for Radicals
3. Using fishhook arrows, show all resonance structures for the compound below.
V
V
V.
Transcribed Image Text:Explain the structure, geometry, and relative stability of carbon radicals. Rank the relative C-H bond strengths within a molecule. Draw resonance structures for carbon radicals. Identify common curved-arrow patterns in radical mechanisms and draw mechanisms for radical reactions using fishhook arrow-pushing patterns. Identify initiation and propagation steps for a radical reaction. Carbon Radical Stability & C-H Bond Dissociation Energy 1. Rank the stability of the carbon radicals below from least stable to most stable. A 2. Within each molecule below, rank the C-H bonds indicated from weakest to strongest. The weaker the bond, the more stable the radical formed upon homolytic cleavage. HA Hc Hg HA HB Resonance for Radicals 3. Using fishhook arrows, show all resonance structures for the compound below. V V V.
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