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- The specific heat of an unknown liquid is determined using a sample of molybdenum (Mo) with a mass of 35.12g. The Mo is heated to 99.2OC in boiling water, and then transferred to 52.16g of unknown liquid whose temperature is 23.4OC. The final temperature of the Mo-unknown liquid system is 28.9OC. Calculate the specific heat of the unknown liquid. CMo = 0.251 J•g-1•OC-1The specific heat of compound AB(s) was determined using coffee-cup calorimeter. When 1.750 g of AB(s) was mixed with 15.00 mL deionized distilled water at room temperature, only 0.850 grams of the compound was dissolved. The temperature of the heterogenous mixture was decreased by 1.70K.Prior to this, the calorimeter was calibrated using a 15mL aqueous reaction mixture that initially contains 0.070 moles each of HBr and KOH. The recorded ΔT is +5.75K. Note: H+(aq) + OH -(aq) → H2O(l) ΔH = -55.85 kJ/molAB(s) ⇌ A+(aq) + B-(aq) ΔH = 88.75 kJ/molspecific heat (H2O) = 4.184 J/g°CMM of AB = 65 g/mol What is the specific heat of solid AB compound (in J/g°C)?4.38 g of a gas (28.1 g mol–1) was dissolved in liquid water in a calorimeter with a calorimeter constant of 76.0 J K–1. Prior to mixing everything was equilibrated to 21.2 °C. The resulting solution with a mass of 23.4 g was observed to be at a temperature of -6.8 °C and have a specific heat capacity of 4.61 J g–1 K–1. Determine q per mole for this dissolution process. a. -5150 J/mol b. -1.94 × 104 J/mol c. 2.89 × 105 J/mol d. -3.39 × 105 J/mol e. 3.30 × 104 J/mol
- Determination of enthalpy of neutalisation Ccal=20 J/°C Volume of HCl = 150 ml Initial temperature of HCl = 30 °C Volume of NaOH = 149 ml Initial temperature of NaOH = 30 ° C Final Solution Temperature = 45 °C Moles of H+ = .220 mol Moles of OH- = .221 mol Limitng reagent = OH- Heat transfer of solution = ___________|Kj Enthalpy of neutralisation per mole of limiting reagent = _____________________|kj/ molA coffee-cup (constant pressure) calorimeter is used to carry out the following reaction in 68.5 mL water (where X is a hypothetical metal): X + 2 HCI ---> XCI2 + H2 In this process, the water temperature rose from 25.0 °C to 33.3 °C. If 0.00629 mol of "X" was consumed during the reaction, what is ?rH of this reaction in kJ mol^-1with respect to "X"? The specific heat of water is 4.184 J g-¹ °C-¹1. Calculate the standard enthalpy of formation of C10H10. Its standard enthalpy of combustion is shown by the equation: 2C10H10 (l) + 25O2 (g) → 20CO2 (g) + 10H2O (l) ∆H = 10,314 KJ/mol The standard heat of formation (KJ/mol) at 298.15oC : CO2 = -393.5 ; H2O(l) = -285.8 2. Determine ΔG° at 298.15K for the reaction: 4Fe (s) + 3O2 (g) → 2Fe2O3 (s) Given that ΔH° = -1648 kJ ; ΔS° = -549.3 J/K 3. In the picture, Find the the ∆H°rxn if ∆G°rxn is 420 kJ/mol and ∆S°rxn is -143 J/mol*k
- A student poured 100 ml of water (density = 1.00 g / mL) into a coffee calorimeter, noted that the temperature of the water was 18.8oC, then added 5.33 g KOH. With the lid on, the mixture was stirred, temperature increased and the maximum temperature reached at the time of mixing 31.6 oC. Calculate the heat of the system in this dissolution reaction (qsys). ( Approximate the specific heat capacity, cp as 4.18 J g-1 K-1. Do not consider the contribution to the heat generated from the calorimeter; assume that this is zero. Only calculate the heat from the heat capacity of the solution. make sure you consider the sign of qsys qsys for dissolution of KOH = JA student was asked to determine the enthalpy of solution of KclO3 in water using Styrofoam calorimetry. Calibration was performed by mixing 8.00 mL 0.050 M HCI with 2.00 mL 0.200 M NaOH. The neutralization reaction (AH = -55.85 kJ/mol) was accompanied by a temperature change from 25.0 to 28.3°C. Using the same calorimeter, 0.300 g KCIO3 (MW: 122.55) was dissolved in water and the temperature was observed to change from 23.6 to 17.3°C. (Assume that the total volume of the mixture in calibration is the same in the enthalpy measurement) What is the calorimeter constant in kJ/°C? What is the enthalpy of dissolution of KCIO3 in kJ/mol?To determine the specific heat of a newly created, highly conducting material, a 704.8 mg sample of the material was supplied with 35.548 J of heat causing the temperature of the material to rise from 297.05 K to 461.4 K. What is the specific heat of this material? Report your answer in units of J/(ºC · g) to 4 sig figs, but do NOT include units in your answer.
- Estimate the thermal properties of a food with the following composition: carbohydrate 0.3%, protein 27.6%, fat 17.5%, ash 4.7%, moisture 49.9%. a. Specific heat is based on the Siebel equation = kJ / kg ° C. b. Specific heat is based on the Charm equation = kJ / kg ° C. c. Specific heat is based on the Heldman & Singh equation = kJ / kg ° C. d. Specific heat is based on the Choi & Okos equation = kJ / kg ° C. e. Heat conductivity is based on the equation Sweat = W / m ° C. f. Heat conductivity is based on the Choi & Okos equation = W / m ° C. g. Heat diffusivity based on the Choi & Okos equation = m² / s.At constant pressure and 25^C, What is delta H for the following reaction. 2C2H6(g) + 7O2(g) = 4CO2(g) + H2O(l) if the complete consumption of 38.2 g of C2H6 libraties 1981 KJ of heat energy?A pellet of benzoic acid standard was combusted in a bomb calorimeter to determine the experimental calorimeter constant. After 6 mins of monitoring the temperature, the bomb was fired. The following data were obtained. mole of benzoic acid: 0.0049 mol mass of burnt fuse wire: 0.0125 g qwire,surr: 5858 J/g ΔHcombustion of benzoic acid: -3228.0 kJ/mol Δng (combustion of benzoic acid): -0.5 mol R: 8.314 J/mol•K r1: 0ºC/min r2: 0ºC/min Tf: 30.4ºC Ti: 28.4ºC Determine the calorimeter constant (in J/ºC). Report your answer in 2 decimal places.