1. Which among these is/are desirable properties for the type of precipitate required ingravimetric analysis?I. large particlesIII. known compositionA. I onlyII. reactive with atmospheric constituentsIV. small particlesC. I & IIIВ. I & IID. III & IVЕ. I, П, I

Gravimetric analysis is used to determine the mass or concentration of a substance by measuring a…

Answered: 1. Which among these is/are desirable…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter16: Solubility And Precipitation Equilibria

Section: Chapter Questions

Problem 52P

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The chloride in the sample is to be determined gravimetrically by precipitating and weighing AgCl. What weight in grams of sample should be taken so that the percentage of Cl is obtained by simply multiplying the weight of the AgCl precipitate by 10?
(a) I f t he molar solubilit y o f CaF2 at 35 °C i s1.24 x 10-3 mol/L, what is Ksp at this temperature? (b) It isfound that 1.1 x 10-2 g SrF2 dissolves per 100 mL of aqueoussolution at 25 °C. Calculate the solubility product forSrF2. (c) The Ksp of Ba(IO3)2 at 25 °C is 6.0 x 10-10. What isthe molar solubility of Ba(IO3)2?
Sources of Error Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided. TOPIC: Measured mass of the precipitate 1. Overignition which causes the conversion of BaSO4 precipitate to BaO. EX _____ ET2. Precipitate was not washed thoroughly. Ex _____ ET TOPIC: Standardization of Titrant 3.Distilled water was not equilibrated to room temperature before the preparation of NaOH titrant. EX _______ ET
True or False Very Insoluble precipitates are not the best candidates for gravimetric analysis.
A 0.64 g sample containing KCl ( mw = 74.6 ) is dissolved in 50mL of water and titrated to the Ag2CrO4 end point, requiring 26.2 mL of 0.15 M AgNO3 .The %w/w KCl in the sample is ?
A suitable target for the titration is 30.0 cm3 of 0.025 moldm-3 Br2(aq) Justify why a much smaller target titre would not be appropriate Calculate the amount in moles of bromine in the target titer Justification? calculate a suitable massof alive oil to transfer to the volumetric flask using your answer to of above question and the structure of Y Assume that the olive oil contains 85/- of Y by mass (If you were unable to calculate the amount of bromine in the target titer,you should assume it is 6.25×10^-8 mol .this in not the correct amount)
What is the maximum solid solubility of Mg in Al? At what temperature does it occur? e. An Al-Mg alloy (10 wt% Mg, 90 wt% Al) is heated slowly (to insure equilibrium) from a temperature of 200 C: i. At what temperature does the first liquid phase form? ii. What is the composition of the liquid phase at the temperature in part i.? iii. At what temperature does complete melting (no solid phase remaining) occur? iv. What is the composition of the last solid remaining prior to complete melting? f. Using the equilibrium phase diagram of Figure 1, identify the phases present, their compositions, and their relative mass fractions at equilibrium for a 70 wt% Mg – 30 wt% Al alloy held at 300 C.
The compound lead(II) sulfate has a solubility of 4.824E-3 g/100mL at 25 degC.What is the molar solubility of this solution at saturation? 0.0002 mol/L What is the Ksp at 25 degC for lead(II) sulfate? What is the molar solubility of lead(II) sulfate in 0.28 M lead(II) nitrate ?
It is required to know the concentration of an aqueous solution of H2SO4 that appeared in the laboratoryChemistry III and it's unlabeled. To this end, a student of analytical chemistry carried out the followingProcedure: He took 5.00 mL of a fresh and standardized solution of 0.525M NaOH and brought them to a250.0 mL balloon to be completed with distilled water. Subsequently, he poured 15.00 mL of the solutionH2SO4 of unknown concentration in an Erlenmeyer flask and added 2 drops of phenolphthalein.Using a burette filled with the last NaOH solution, he noticed that when adding 39.40 mL of the hydroxidethe Erlenmeyer solution reached a faint but permanent pink. With the above dataDetermine the concentration and pH of the H2SO4 solution.
How would you use an experimentally determined Ksp value to calculate that Ag2CrO4 should precipitate when 5ml of 0.0040 M AgNO3 are added to 5ml of 0.0024 M K2CrO4. You can come up with your own experimentally Ksp value. I just want to see steps in solving
123 mL of a 0.352 M Ca(NO3)2 solution is mixed with 251 mL of a 0.254 M solution of NaF at 25ºC. Calculate Qsp for the precipitate formed.
3. To 20,00 ml of 0,1250 mol/l solution of silver nitrate – 25,00 ml of 0,1000 mol/l solution of potassium thiocyanate were added. Calculate pAg of this mixture. pKs(AgSCN) = 11,97 Express numerical result with an accuracy of: Х,ХX

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1. Which among these is/are desirable properties for the type of precipitate required in gravimetric analysis? I. large particles III. known composition A. I only II. reactive with atmospheric constituents IV. small particles C. I & III В. I & II D. III & IV Е. I, П, I