Answered: 1. Work out the symmetry point group of…

Science

Chemistry

1. Work out the symmetry point group of the following (any two). (i) S,0; (ii) allene (iii) IF5

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.30E: Structural isomers can have very different point groups. Determine the point groups of...

See similar textbooks

Related questions

Q: Determine the point groups of the following molecule: XeF4

A: A point group express all the symmetry operations that can be execute on a molecule that result in a…

Q: Please explain Point group symmetry for a molecule with hexagonal symmetry such as bilateral…

A: The hexagonal symmetry means that the molecule must have the C6 rotation symmetry element. It is…

Q: XeF4 has a molecular geometry of square planar. i. How would you determine its point group? ii.…

A: XeF4 has planar geometry in which Xe present at the cut point of two diagonals of the square and 4…

Q: cis-C2H2Cl2 belongs to C2v point group. Using the C2v character table in the picture, i. Find the…

A: Given : We have to determine the the reducible representation of cis-C2H2Cl2.

Q: 4. Explain what you understand when it comes to symmetry, symmetry element and point groups, giving…

A: Symmetry: Symmetry is characterized as a decent and proportionate similitude that is found in two…

Q: Please provide the POINT GROUPS of the following objects and explain why.

Q: Find all the symmetry elements in the following molecule: XeF2

A: σhIn order to determine the symmetry elements of a molecule we need to know its shape. The central…

Q: Determine the point groups for a triangular prism .

A: Point group: It is used to detect the all symmetry elements existing in the molecules which helps in…

Q: Determine the point group of the molecule shown. Make OS sure to rotate the molecule to see all of…

A: SF6 comes into the special category of molecules. It has regular octahedral geometry. Molecules with…

Q: Determine the point groups for The possible isomers of tribromobenzene .

A: The structure of chemical compound can be represented as structural formula. A structural formula…

Q: 2) 2) Below is a “ball and stick" representation of the molecule CH4. Assume all bond lengths and…

Q: 2. Please draw the structures of the following molecules, and determine their point groups: a)…

A: Answers are explained below: a) The structure of [SO3]2- is as follows:

Q: Verify the point groups of the following molecule : F2

A: Point group basically depicts the 3D arrangement of a molecule using symmetry elements, such as axis…

Q: Can molecules belonging to the point groups D2h or C3h be chiral? Explain your answer.

Q: Molecular Geometry Symmetry Elements Point Group (Shape) Molecules 1. CO 2. CC, (Not planar) 3.…

Q: Chemistry for this in phase fully bonded phasing combination, determine: point group? # of bonding…

A: 1.Point group of IrH6 is octahedral (Oh)

Q: what is the point group symmetry of the following molecule? CI N.

A: Point group symmetry of a compound is determined by its symmetry elements.

Q: Determine the point group of the following orbital:

A: The given orbital is f0 orbital

Q: 1) For each of species, write down all symmetry operations, and the highest symmetry point group A A…

A: A symmetry operation is an activity that, once completed, leaves a molecule or item with the same…

Q: Determine the point group of the molecule shown.

A: Step : 1 Determine the point group of PCl3F2.

Q: NO3- (d3h) MO diagram.. needed in irreducible form

Q: Determine the point group for the following molecule: OCM CO CO

A: The organometallic compound contains the principle axis C3.

Q: determine the symmetry adapted linear combinations of borane BH3

Q: Which of the following would be expected to have a dipole moment of zero on the basis of symmetry?…

A: The molecule that is expected to have a dipole moment of zero on the basis of symmetry has to be…

Q: What point groups result from the combination of two mirror planes oriented at 90° with respect to…

A: Point group tells about the symmetry within a molecule. The following symmetries can be present…

Q: Determine the Point group of the following molecule. Cr

A: A point group is a group of geometric symmetries that keep at least one point fixed. Point groups…

Q: Molecule/lon Geometry of molecule Key symmetry elements Point group B(F)(CI)(Br) [S2O3

A: The general shape of the molecule is depicted by the geometry of the molecule. There are various…

Q: Nz 0. & NO,

Q: In which point group are the letters A, F, N respectively? a) C2v, C2v, D2h b) C2v, C2v, C2v…

A: The letters A, F, N are the Mulliken symbols that represent the symmetry elements present in a…

Q: Please draw the structure of the following molecule and determine their point groups

A: From the structure of SO3 2-, we see that the structure is a symmetrical Trigonal planar structure.…

Q: 2. Consider IF:O2 (with I as the central atom). How many isomers are possible (draw them)? Which is…

A: The chemical name of IF3O2 is iodine fluoride oxide. It has 5 sets of electron pairs around the…

Q: 3. For Dan, use sketches of the orbitals to show that d., have B2g symmetry i.e. show how the…

A: D4h is a point group with the symmetry elements - E, σh , 4σv , C4, 4C2 D4h have 1 horizontal…

Q: Determine the point group for each compölünd

Q: What is the symmetry point group for cis-[PtBr2Cl2]2-? O a. C2v O b. D4h O c. D2h O d. C2h

A: What is the symmetry point group for the given complex---

Q: Which of the following would be expected to have a dipole moment of zero on the basis of symmetry?…

A: All symmetrical molecules have diople moment equal to zero and are considered as non-polar whereas…

Q: 4 Considering the carbonate atomic (CO32- ) construct the SALCS. 1) Make a table that has each…

A: Solution- the carbonate atomic (CO32- ) construct the SALCS. 1) We have to make a table that has…

Q: 1. Work out the symmetry point group of the following (any two). (i) S,0, (ii) allene (iii) IFs

A: This Question is based upon group theory. According to question any two point group has to be given.

Q: I. Determine the point groups of the following: (found in NH, 1,) A. Tetrafluorocubane B D.…

A: Point group symmetry of elements. Tetra fluoro cubane is having C2 axis of symmetry. Staggered…

Q: How many symmetry planes does p-dibromobenzene have? O 1 2 3 4

A: A plane of symmetry is a symmetry element. The plane of symmetry is defined as a flat surface that…

Q: (a) Complete the following table: Molecule/lon Geometry of molecule Key symmetry elements Point…

A: 1) B(F)(Cl)(Br) The given compound has 3 bond pairs and 0 lone pairs on the central atom. Thus it is…

Q: Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have: (i)…

Q: 2. Molecular symmetry a. Determine the symmetry operations of the molecule Ni(NH3),* and assign the…

Q: [CHS] + is in the Cs point group: Draw the reducible representation of the 5 hydrogens Character…

A: This point group contains only two symmetry operations: E the identity operation, σ a mirror plane.…

Q: (c)) A partial character table for C3y point group is given as C30 E 2C3 30, 1 1 1 1 -1 ? -1 Assign…

A: A character table can be defined as a two-dimensional table whose rows correspond to irreducible…

Q: Determine the point group of the molecule shown. Be sure to rotate the molecule so that you can see…

Q: 2) Use the C2 point group to illustrate that the irreducible representations in a character table…

A: The character table for the C2 point group is shown below.

Q: 2- SO 3. 2- 1)

Q: d) Borazina, HN `NH HB. BH e) [tris(pirazolil)borat]" H ZI

A: A symmetry operation is an action which when performed on a molecule yields a new orientation of it…

Q: Can molecules belonging to the point groups Th or Td be chiral? Explain your answer.

A: A molecule will be symmetric the molecule is indistinguishable form the initial structure after a…

Question

1. Work out the symmetry point group of the following (any two).
(i) S,0; (ii) allene (iii) IF5

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.
In your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.
a In the Td point group, an S41 improper rotation is equivalent to what other improper rotation? b In the D6h point group, the symmetry operation labeled C21 is equivalent to what other symmetry operation?
Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal structure, b CO32, which has three resonance structures that contribute to its overall shape, c The perfectly staggered conformation of ethane, d The perfectly eclipsed conformer of ethane.
Identify the symmetry elements present in the following objects. a The Eiffel Tower. You may have to look up a picture of it if you dont remember its shape b Any book ignore the printing. c An octagonal wood block. d A jack from the set of jacks pictured here: Note that some of the points end differently.
Determine the point group of the following molecules. a cis1,2 Dichloroethylene b trans1,2 Dichloroethylene c Toluene, C6H5CH3 d 1,3-Cyclohexadiene.
Determine which single symmetry operation of the following point groups is equivalent to the given combination of multiple symmetry operations. a In C2v, C2v=? b In C2h, iC2=? c In D6h, C6h=? d In D2d, C2C2=? e In Oh, iS4=?
Why is it unnecessary to consider whether an irreducible representation from C4h is orthogonal to an irreducible representation of D6h?
Structural isomers can have very different point groups. There are three isomers of dichlorobenzene. Identify the point groups of the three isomers.
Identify the symmetry elements present in the following objects. a A ream of blank paper, no holes. b A ream of blank three-holed paper. c A round pencil, unsharpened, with cylindrical eraser. d A round pencil, sharpened, with cylindrical eraser.
Show that any two of the irreducible representations of the following point groups are orthogonal to each other. a C2 b C2v c D2h d Oh e Td
Determine the symmetry species of the D3h point group for the sp2 hybrid orbitals, assuming that the C3 axis is coincident with the z-axis and that one of the orbitals lies along the positive x-axis. See Example 13.16.