1.Bearing in mind the melting-point values reproduced below, suppose you formulate a product to be sold as a margarine substitute that contains 20% sodium oleate and 80% sodium palmitate, plus trace amounts of colorants and odorants. How would the properties of this formulation change if you were to increase the percentage of unsaturated fatty acid to 40%?

EBK A SMALL SCALE APPROACH TO ORGANIC L
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Chapter87: Steam Distillation
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1.Bearing in mind the melting-point values
reproduced below, suppose you formulate a
product to be sold as a margarine substitute
that contains 20% sodium oleate and 80%
sodium palmitate, plus trace amounts of
colorants and odorants. How would the
properties of this formulation change if you
were to increase the percentage of unsaturated
fatty acid to 40%?
lIUPAC
Name
Molecular
Melting Point,
°C
# of
# of
Common
Carbons double bonds name
formula
lo
Laurate
Dodecanoate
CH3(CH2)10CO0
44
12
Myristate
Tetradecanoate
CH3(CH2)12C00
CH3(CH2)14CO0
CH3(CH2)16CO0
14
lo
52
16
Palmitate
Hexadecanoate
63
18
Stearate
Octadecanoate
70
Arachidate
Eicosanoate
CH3(CH2)18CO0
CH3(CH2)20CO0
20
75
22
Behenate
Docosanoate
81
24
LignocerateTetracosanoate
CH3(CH2)22CO0
84
Palmitoleate cis-A-Hexadecenoate
CH3(CH2)5CH=CH(CH2)7C00
CH3(CH2)7CH=CH(CH2)7CO0
16
1.
-0.5
Oleate
cis-A9-Octadecenoate
13
18
Linoleate
-Octadecadienoate
CH3(CH2)4(CH=CHCH2)2(CH2)6CO09
18
cis,cis-A9, 12
18
3
Linolenate
all cis-A9, 12,15 Octadecatrienoate CH3CH2(CH=CHCH2)3(CH2)6CO0
|-17
20
4
Arachidonate all cis-A5,8,11,14 Eicosatetraenoate CH3(CH2)4(CH=CHCH2)4(CH2)2CO0|-49
Transcribed Image Text:1.Bearing in mind the melting-point values reproduced below, suppose you formulate a product to be sold as a margarine substitute that contains 20% sodium oleate and 80% sodium palmitate, plus trace amounts of colorants and odorants. How would the properties of this formulation change if you were to increase the percentage of unsaturated fatty acid to 40%? lIUPAC Name Molecular Melting Point, °C # of # of Common Carbons double bonds name formula lo Laurate Dodecanoate CH3(CH2)10CO0 44 12 Myristate Tetradecanoate CH3(CH2)12C00 CH3(CH2)14CO0 CH3(CH2)16CO0 14 lo 52 16 Palmitate Hexadecanoate 63 18 Stearate Octadecanoate 70 Arachidate Eicosanoate CH3(CH2)18CO0 CH3(CH2)20CO0 20 75 22 Behenate Docosanoate 81 24 LignocerateTetracosanoate CH3(CH2)22CO0 84 Palmitoleate cis-A-Hexadecenoate CH3(CH2)5CH=CH(CH2)7C00 CH3(CH2)7CH=CH(CH2)7CO0 16 1. -0.5 Oleate cis-A9-Octadecenoate 13 18 Linoleate -Octadecadienoate CH3(CH2)4(CH=CHCH2)2(CH2)6CO09 18 cis,cis-A9, 12 18 3 Linolenate all cis-A9, 12,15 Octadecatrienoate CH3CH2(CH=CHCH2)3(CH2)6CO0 |-17 20 4 Arachidonate all cis-A5,8,11,14 Eicosatetraenoate CH3(CH2)4(CH=CHCH2)4(CH2)2CO0|-49
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