10 mol % Pd(OAc)2 BUNCI, K₂CO DMF, 100 °C OMe Pd(OAc)2 PhyP (20%) BC Reaction 2 BnO₂C7 OBn MeOOC Identify the structure of Reaction 1's for product A. Explain Reaction 1's mechanism. Justify the product's stereochemistry for A. For Reaction 2, predict the structure of B and C. Clarify your answer. OBn A (10%) Reaction 1

10 mol % Pd(OAc)2 BUNCI, K₂CO DMF, 100 °C OMe Pd(OAc)2 PhyP (20%) BC Reaction 2 BnO₂C7 OBn MeOOC Identify the structure of Reaction 1's for product A. Explain Reaction 1's mechanism. Justify the product's stereochemistry for A. For Reaction 2, predict the structure of B and C. Clarify your answer. OBn A (10%) Reaction 1

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter10: Organohalides

Section10.2: Preparing Alkyl Halides From Alkanes: Radical Halogenation

Problem 4P: Taking the relative reactivities of 1Â°, 2Â°, and 3Â° hydrogen atoms into account, what product(s)...

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Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?
when H2O2 is added into acidified K2Cr2O7 which colour appears?
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Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides.One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(C2H5)3). 3SnCl4 + 4Al(C2H5)3 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.230 L of SnCl4 (d = 2.226 g/mL) was treated with 0.396 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). If 0.335 L of tetraethylstannane (d = 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?
Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):
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! (plz give proper explanation)