10) The dimerization of butadiene was studied at 500. K: 2C4H6 (g) →C8H12 (g) The following rate data were obtained: Rate= d[CH] dt Time (s) [CH] (mol/L) 195 1.6 x 10-2 604 1.5 × 10-2 1246 1.3 x 10-2 2180 1.1 x 10-2 6210 0.68 × 10-2 Determine the forms of the differential and integrated rate law, the value for the rate constant, and the reaction half-life.

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 43E: The dimerization of butadiene 2C4H6(g)C8H12(g) was studied at 500. K, and the following data were...
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10) The dimerization of butadiene was studied at 500. K:
2C4H6 (g) →C8H12 (g)
The following rate data were obtained:
Rate=
d[CH]
dt
Time (s)
[CH] (mol/L)
195
1.6 x 10-2
604
1.5 × 10-2
1246
1.3 x 10-2
2180
1.1 x 10-2
6210
0.68 × 10-2
Determine the forms of the differential and integrated rate law, the value for the rate
constant, and the reaction half-life.
Transcribed Image Text:10) The dimerization of butadiene was studied at 500. K: 2C4H6 (g) →C8H12 (g) The following rate data were obtained: Rate= d[CH] dt Time (s) [CH] (mol/L) 195 1.6 x 10-2 604 1.5 × 10-2 1246 1.3 x 10-2 2180 1.1 x 10-2 6210 0.68 × 10-2 Determine the forms of the differential and integrated rate law, the value for the rate constant, and the reaction half-life.
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