Experiment shows that the rate formation of carbon tetrachloride from chloroform,CH3 +Cl2 → CCl4 + HCIis the first order in CHCl3, ½ order in Cl2 and 3/2 order overall. Is the followingmechanism consistent with the overall rate low?Cl2 2 Cl(K1, K-1)fastCl + CHCl 3 → HCI + CC13⚫(k2)slowCCl3 + Cl⚫CCl4(K3)fast(Use the steady state principle for the radicals Cl• and CC13. to determine thedifferential rate equation of carbon tetrachloride formation d [CCl4] / dt).

Step 1:To determine if the proposed mechanism is consistent with the observed rate law, let's…

Answered: Experiment shows that the rate…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section11.3: Rate Law And Order Of Reactions

Problem 11.4PSP

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