10.5. The rate of formation of the product of a reaction is found to give a nonlinear Arrhenius plot, the line being convex to the 1/T axis (i.e., the activation energy is higher at higher temperatures). Suggest a reason for this type of behavior. (Hint: For this and the following problem, consider the possibility of two parallel reactions and of two consecutive reactions having different activation energies.)
10.5. The rate of formation of the product of a reaction is found to give a nonlinear Arrhenius plot, the line being convex to the 1/T axis (i.e., the activation energy is higher at higher temperatures). Suggest a reason for this type of behavior. (Hint: For this and the following problem, consider the possibility of two parallel reactions and of two consecutive reactions having different activation energies.)
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.49PAE: The rate of photodecomposition of the herbicide piclo- ram in aqueous systems was determined by...
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