100 H3C 80 60 40 CH3 H3C 20 H3C H;c+ 0.0- 0.0 15 30 45 60 75 90 m/z Figure 3. Positive ion mass spectrum of methyl acetate. Note that the peak with the greatest relative intensity is not that of the parent ion fragment. Note in Figure 3. that the peaks corresponding to m/Z = 29 and 42 correspond to fragments which resulted from more than a single bond-breaking event. Rel. Intensity

100 H3C 80 60 40 CH3 H3C 20 H3C H;c+ 0.0- 0.0 15 30 45 60 75 90 m/z Figure 3. Positive ion mass spectrum of methyl acetate. Note that the peak with the greatest relative intensity is not that of the parent ion fragment. Note in Figure 3. that the peaks corresponding to m/Z = 29 and 42 correspond to fragments which resulted from more than a single bond-breaking event. Rel. Intensity

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter20: Molecular Mass Spectrometry

Section: Chapter Questions

Problem 20.9QAP

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