11. From the data in Table 4-1 calculate the heat of combustion of C¿H¿OH(g) t 25°C.

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Chapter6: Thermochemistry
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Problem 68E: In a coffee-cup calorimeter, 1.60 g NH4NO3 is mixed with 75.0 g water at an initial temperature of...
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TABLE 4-1. STANDARD HEats Of FORMATION OF COMPOUNDS AT 25°C
AHO
ΔΗ
Substance
(cal mole-!)
Substance
(cal mole-1)
H;0(1)
H;0(g)
HCl(g)
HBr(g)
HI(g)
HNO,(1)
H;S0.(1)
H;S(g)
CO(g)
CO:(g)
NH:(g)
NO(g)
NO:(g)
SO:(g)
So:(g)
- 68,320
-57,800
- 22,060
-8,660
6,200
- 41,400
- 193,910
-4,820
- 26,420
- 14,050
-11,040
21,600
8,090
- 70,960
- 94, 450
Ag:0 (s)
Cu0 (s)
Fe)(s)
Fe,O:(s)
Fe,0.(s)
NaCl(s)
KCI(s)
AgCl (s)
NaOH (s)
KOH (s)
AGNO,(8)
Na:SO,(s)
PbS0, (s)
Na:CO,(s)
CaCO,(s)
-7,310
-38, 500
- 64, 300
- 196,500
- 267,000
-98,230
- 104, 180
-30,360
- 102,000
- 102,000
- 29,400
- 330,500
-219,500
-270,300
- 288,450
Methane(g), CH,
Ethane (g), C,H.
Propane(g), C,H,
п-Butane(g), C,Hю
п-Нехапe (в), СHи
n-Octane(g), C.H18
Ethylene(g), C:H,
-17,890
- 20,240
- 24,820
- 29,810
-39,960
- 49,820
12,500
Acetylene(g), C2H2
Benzene (1), C.H.
Naphthalene (s), C10H
Methanol (1), CH;OH
Echanol(g), C,H,он
Еthancl(1), C,H.он
Аcetic Acid (l), CH,CООН —116,400
54,190
11,720
14,400
-57,020
- 56,300
- 66,360
Transcribed Image Text:TABLE 4-1. STANDARD HEats Of FORMATION OF COMPOUNDS AT 25°C AHO ΔΗ Substance (cal mole-!) Substance (cal mole-1) H;0(1) H;0(g) HCl(g) HBr(g) HI(g) HNO,(1) H;S0.(1) H;S(g) CO(g) CO:(g) NH:(g) NO(g) NO:(g) SO:(g) So:(g) - 68,320 -57,800 - 22,060 -8,660 6,200 - 41,400 - 193,910 -4,820 - 26,420 - 14,050 -11,040 21,600 8,090 - 70,960 - 94, 450 Ag:0 (s) Cu0 (s) Fe)(s) Fe,O:(s) Fe,0.(s) NaCl(s) KCI(s) AgCl (s) NaOH (s) KOH (s) AGNO,(8) Na:SO,(s) PbS0, (s) Na:CO,(s) CaCO,(s) -7,310 -38, 500 - 64, 300 - 196,500 - 267,000 -98,230 - 104, 180 -30,360 - 102,000 - 102,000 - 29,400 - 330,500 -219,500 -270,300 - 288,450 Methane(g), CH, Ethane (g), C,H. Propane(g), C,H, п-Butane(g), C,Hю п-Нехапe (в), СHи n-Octane(g), C.H18 Ethylene(g), C:H, -17,890 - 20,240 - 24,820 - 29,810 -39,960 - 49,820 12,500 Acetylene(g), C2H2 Benzene (1), C.H. Naphthalene (s), C10H Methanol (1), CH;OH Echanol(g), C,H,он Еthancl(1), C,H.он Аcetic Acid (l), CH,CООН —116,400 54,190 11,720 14,400 -57,020 - 56,300 - 66,360
11. From the data in Table 4–1 calculate the heat of combustion of C,H,OH(g)
at 25°C.
12. From the data in Table 4-3 determine at 25°C:
(a) The amount of heat which will be liberated when 2 moles of H,SO.(1)
are dissolved in 30 moles of H,0(1)
(b) The differential heats of solution of the acid and the water for the given
solution.
Transcribed Image Text:11. From the data in Table 4–1 calculate the heat of combustion of C,H,OH(g) at 25°C. 12. From the data in Table 4-3 determine at 25°C: (a) The amount of heat which will be liberated when 2 moles of H,SO.(1) are dissolved in 30 moles of H,0(1) (b) The differential heats of solution of the acid and the water for the given solution.
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