11. The net reaction for formation of HI from H2 and I2 is H, +I, 2 2HI The following mechanism was proposed for this reaction I= 21 H,I k k_1 Н, +I k_2 H,I +I- 2HI Using the preequilibrium approximation, derive the predicted rate law expression for the above mechanism: A) 2k3K¡K2[H2][I2] B) 2k;K2[H2][I2] C) 2k3KiK2[H2][I] D) 3k3K2[H2][I] E) 2K¡K2[H2]

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.7: Reaction Mechanisms
Problem 2.2ACP
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11. The net reaction for formation of HI from H2 and I2 is
H, +I, A 2HI
The following mechanism was proposed for this reaction
k
I,
k_1
21
H, +I H,I
H,I + I–
Using the preequilibrium approximation, derive the predicted rate law expression for
→2HI
the above mechanism:
A) 2k;K,K2[H2][L]
B) 2k3K2[H2][I2]
C) 2k3K,K2[H2][I]
D) 3k3K2[H2][I]
E) 2K,K2[H2]
Transcribed Image Text:11. The net reaction for formation of HI from H2 and I2 is H, +I, A 2HI The following mechanism was proposed for this reaction k I, k_1 21 H, +I H,I H,I + I– Using the preequilibrium approximation, derive the predicted rate law expression for →2HI the above mechanism: A) 2k;K,K2[H2][L] B) 2k3K2[H2][I2] C) 2k3K,K2[H2][I] D) 3k3K2[H2][I] E) 2K,K2[H2]
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