6. Complex Polymer Growth a. Propose a synthesis of the following compound using a commercial carboxylic acid functionalized azo-initiator, ACVA (structure shown below), and any other reagents you may need: NC- CN HOOC, CN COOH NC NC N=N -CN b. Using the above initiator to polymerize methyl methacrylate you find that termination occurs 0.02% as frequently as monomer addition. What would you expect Mn to be (Mo = 100.1 g/mol)?
6. Complex Polymer Growth a. Propose a synthesis of the following compound using a commercial carboxylic acid functionalized azo-initiator, ACVA (structure shown below), and any other reagents you may need: NC- CN HOOC, CN COOH NC NC N=N -CN b. Using the above initiator to polymerize methyl methacrylate you find that termination occurs 0.02% as frequently as monomer addition. What would you expect Mn to be (Mo = 100.1 g/mol)?
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.36P
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