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13. Which reagents above are used for elimination reactions? Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NANH, (or NaH) NaNH2 (excess) 1. NANH2 (3 eq) 2. H,O H2, Pt (or Pd) H2, Lindlar Na, NH3 H9SO4, H2SO4, H20 1. R,BH (like (sia),BH or 9-BBN) 2. H2O2, NaOH HBr (1 eq) NAOME KОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H2SO4 (concentrated, sometimes shown with heat or A) На, Pt (or Pd) | X2 like Br2 Br2, H2O H2SO4, H2O (or “dilute sulfuric acid," or H3O*, or H*, H2O) HBr (excess, or 2 eq) Br2 (1 eq) Br2 (excess, or 2 eq) Br2, hv HBr, ROOR HBr 1. Hg(OAc)2, Н,0 2. NaBH, 1. ВН, 1. O3 1. OsO4 2. NaHSO:, H2O mcpba (or RCO;H) 2. H2O2, NaOH 2. DMS ((CH:)2S) (or Zn/H2O)

13. Which reagents above are used for elimination reactions? Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NANH, (or NaH) NaNH2 (excess) 1. NANH2 (3 eq) 2. H,O H2, Pt (or Pd) H2, Lindlar Na, NH3 H9SO4, H2SO4, H20 1. R,BH (like (sia),BH or 9-BBN) 2. H2O2, NaOH HBr (1 eq) NAOME KОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H2SO4 (concentrated, sometimes shown with heat or A) На, Pt (or Pd) | X2 like Br2 Br2, H2O H2SO4, H2O (or “dilute sulfuric acid," or H3O*, or H*, H2O) HBr (excess, or 2 eq) Br2 (1 eq) Br2 (excess, or 2 eq) Br2, hv HBr, ROOR HBr 1. Hg(OAc)2, Н,0 2. NaBH, 1. ВН, 1. O3 1. OsO4 2. NaHSO:, H2O mcpba (or RCO;H) 2. H2O2, NaOH 2. DMS ((CH:)2S) (or Zn/H2O)

Pushing Electrons
Pushing Electrons
4th Edition
ISBN:9781133951889
Author:Weeks, Daniel P.
Publisher:Weeks, Daniel P.
Chapter3: Mechanisms
Section: Chapter Questions
Problem 104EQ
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13. Which reagents above are used for elimination reactions?
Transcribed Image Text:13. Which reagents above are used for elimination reactions?
Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NANH, (or NaH) NaNH2 (excess) 1. NANH2 (3 eq) 2. H,O H2, Pt (or Pd) H2, Lindlar Na, NH3 H9SO4, H2SO4, H20 1. R,BH (like (sia),BH or 9-BBN) 2. H2O2, NaOH HBr (1 eq) NAOME KОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H2SO4 (concentrated, sometimes shown with heat or A) На, Pt (or Pd) | X2 like Br2 Br2, H2O H2SO4, H2O (or “dilute sulfuric acid," or H3O*, or H*, H2O) HBr (excess, or 2 eq) Br2 (1 eq) Br2 (excess, or 2 eq) Br2, hv HBr, ROOR HBr 1. Hg(OAc)2, Н,0 2. NaBH, 1. ВН, 1. O3 1. OsO4 2. NaHSO:, H2O mcpba (or RCO;H) 2. H2O2, NaOH 2. DMS ((CH:)2S) (or Zn/H2O)
Transcribed Image Text:Reagents sheet provided on exam. Some changes to the reagent sheet may occur. NANH, (or NaH) NaNH2 (excess) 1. NANH2 (3 eq) 2. H,O H2, Pt (or Pd) H2, Lindlar Na, NH3 H9SO4, H2SO4, H20 1. R,BH (like (sia),BH or 9-BBN) 2. H2O2, NaOH HBr (1 eq) NAOME KОBu or KOC(CH)з 1. TsCl, pyridine 2. nucleophile HBr H2SO4 (concentrated, sometimes shown with heat or A) На, Pt (or Pd) | X2 like Br2 Br2, H2O H2SO4, H2O (or “dilute sulfuric acid," or H3O*, or H*, H2O) HBr (excess, or 2 eq) Br2 (1 eq) Br2 (excess, or 2 eq) Br2, hv HBr, ROOR HBr 1. Hg(OAc)2, Н,0 2. NaBH, 1. ВН, 1. O3 1. OsO4 2. NaHSO:, H2O mcpba (or RCO;H) 2. H2O2, NaOH 2. DMS ((CH:)2S) (or Zn/H2O)
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