1,3,5, -Cycloheptatriene (C) can undergo two different electrocyclic ring closures as given below under thermal and photochemical conditions. Identify the mode of rotation (Conrotatory or Dirotatory) in each product D and E. Using Aromatic transition state theory show that both reactions are allowed.

1,3,5, -Cycloheptatriene (C) can undergo two different electrocyclic ring closures as given below under thermal and photochemical conditions. Identify the mode of rotation (Conrotatory or Dirotatory) in each product D and E. Using Aromatic transition state theory show that both reactions are allowed.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

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Problem 34AP: Bicyclohexadiene, also known as Dewar benzene, is extremely stable despite the fact that its...

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1,3,5, -Cycloheptatriene (C) can undergo two different electrocyclic ring closures as given
below under thermal and photochemical conditions. Identify the mode of rotation (Conrotatory
or Dirotatory) in each product D and E. Using Aromatic transition state theory show that both
reactions are allowed.

Definition Definition Organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Aromatic organic compounds, also called arenes, are an important class of hydrocarbons under the branch of organic chemistry.

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