Luminol dianion is treated with hydrogen peroxide and potassium ferricyanide which results in formation of triplet excited state dianion and liberation of nitrogen gas. Once formed, the triplet dianion undergoes intersystem crossing to form a singlet excited state. As the molecule returns to the ground state, it emits bluish-green light. 9. (1) Draw the curved arrow mechanism showing conversion of B to C. (Hint: Think of Diels- Alder reaction mechanism) :0

Organic Chemistry
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Author:John E. McMurry
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Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
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Problem 25VC: The following molecular model of a dimethyl-substituted biphenyl represents the lowest-energy...
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Please explain diels alder mechanism

Luminol dianion is treated with hydrogen peroxide and potassium ferricyanide which results in formation
of triplet excited state dianion and liberation of nitrogen gas. Once formed, the triplet dianion undergoes
intersystem crossing to form a singlet excited state. As the molecule returms to the ground state, it emits
bluish-green light.
9. (1) Draw the curved arrow mechanism showing conversion of B to C. (Hint: Think of Diels-
Alder reaction mechanism)
Transcribed Image Text:Luminol dianion is treated with hydrogen peroxide and potassium ferricyanide which results in formation of triplet excited state dianion and liberation of nitrogen gas. Once formed, the triplet dianion undergoes intersystem crossing to form a singlet excited state. As the molecule returms to the ground state, it emits bluish-green light. 9. (1) Draw the curved arrow mechanism showing conversion of B to C. (Hint: Think of Diels- Alder reaction mechanism)
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