15. At 300 K, the following reaction is found to obey the rate law: Rate = k[NOCI]?: 2NOCI 2NO + CI, Consider the three postulated mechanisms given below. Then choose the response that lists all those that are possibly correct and no others. Mechanism 1 NOCI NO + CI slow CI + NOCI NOCI, fast NOCI, + NO 2NO + Cl2 fast Overall: 2NOCI 2NO + Cl, Mechanism 2 2NOCI NOCI, + NO slow NOCI, NO + Cl, fast Overall: 2NOCI 2NO + Cl2
15. At 300 K, the following reaction is found to obey the rate law: Rate = k[NOCI]?: 2NOCI 2NO + CI, Consider the three postulated mechanisms given below. Then choose the response that lists all those that are possibly correct and no others. Mechanism 1 NOCI NO + CI slow CI + NOCI NOCI, fast NOCI, + NO 2NO + Cl2 fast Overall: 2NOCI 2NO + Cl, Mechanism 2 2NOCI NOCI, + NO slow NOCI, NO + Cl, fast Overall: 2NOCI 2NO + Cl2
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.64PAE: 11.64 HBr is oxidized in the following reaction: 4 HBr(g) + O2(g) —• 2 H2O(g) + 2 Br,(g) A proposed...
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