16. Consider the following half-cells under standard conditions: Electrolyte X* (aq) Y²*(aq) and Y³*(aq) Z* (aq) Half cell Electrode I Metal X II Platinum III Metal Z In an electrochemical cell constructed with half-cell I and half-cell II, the electrode in half-cell II is the negative terminal. In an electrochemical cell constructed with half-cell II and half-cell III, the electrode in half-cell III is negative terminal. Which is the strongest oxidant? A X*(aq) B Y"(aq) Y*(aq) D Z*(aq) 17. Given the standard reduction potentials: E° = +0.960 V NO3 (aq) + 4H* (aq) + 3e¯ = NO (aq) + 2H2O (1) Fe* (aq) + 3e Fe (s) E° = +0.771 V What is E° for the following overall reaction? 4H* (aq) + Fe (s) + NO3 (aq) = Fe* (aq) + NO (aq) + 2H2O (1) A +0.189 V B -1.731 V С 0.189 V D +1.731 V 18. How long would it take to electroplate a box with 28.3 g of silver (107.87 g/mol) at a current of 2.0 A in a solution of AgCl? A 211 min B 844 min C 422 min D 105 min

Chemistry: Principles and Practice
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Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.50QE
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16. Consider the following half-cells under standard conditions:
Electrolyte
X2* (aq)
Y²*(aq) and Y³*(aq)
Z* (aq)
Half cell
Electrode
I
Metal X
II
Platinum
III
Metal Z
In an electrochemical cell constructed with half-cell I and half-cell II, the electrode in half-cell II is the
negative terminal.
In an electrochemical cell constructed with half-cell II and half-cell III, the electrode in half-cell III is
negative terminal.
Which is the strongest oxidant?
A X (aq)
B Y"(aq)
C Y*(aq)
D Z*(aq)
17. Given the standard reduction potentials:
E° = +0.960 V
NO3 (aq) + 4H* (aq) + 3e¯ = NO (aq) + 2H2O (1)
(aq) + 3e = Fe (s)
Fe3+
E° = +0.771 V
What is E° for the following overall reaction?
4H* (aq) + Fe (s) + NO3° (aq)
Fe* (aq) + NO (aq) + 2H2O (1)
A +0.189 V
B -1.731 V
С-0.189 V
D +1.731 V
18. How long would it take to electroplate a box with 28.3 g of silver (107.87 g/mol) at a current of 2.0 A in
a solution of AgCl?
A 211 min
B 844 min
C 422 min
D 105 min
Transcribed Image Text:16. Consider the following half-cells under standard conditions: Electrolyte X2* (aq) Y²*(aq) and Y³*(aq) Z* (aq) Half cell Electrode I Metal X II Platinum III Metal Z In an electrochemical cell constructed with half-cell I and half-cell II, the electrode in half-cell II is the negative terminal. In an electrochemical cell constructed with half-cell II and half-cell III, the electrode in half-cell III is negative terminal. Which is the strongest oxidant? A X (aq) B Y"(aq) C Y*(aq) D Z*(aq) 17. Given the standard reduction potentials: E° = +0.960 V NO3 (aq) + 4H* (aq) + 3e¯ = NO (aq) + 2H2O (1) (aq) + 3e = Fe (s) Fe3+ E° = +0.771 V What is E° for the following overall reaction? 4H* (aq) + Fe (s) + NO3° (aq) Fe* (aq) + NO (aq) + 2H2O (1) A +0.189 V B -1.731 V С-0.189 V D +1.731 V 18. How long would it take to electroplate a box with 28.3 g of silver (107.87 g/mol) at a current of 2.0 A in a solution of AgCl? A 211 min B 844 min C 422 min D 105 min
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