18-Elect Octahedral Complexes are stable, while 16-electron squareplane complexes are stable. Explain according to MOT using [IrCl(CO)(PPh3)2] and [Cr(CO)6].

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter22: The Chemistry Of The Transistion Elements
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18-Elect Octahedral Complexes are stable, while 16-electron squareplane complexes are stable. Explain according to MOT using [IrCl(CO)(PPh3)2] and [Cr(CO)6].

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