18. What is the equilibrium concentration of barium ions in a 1.0L solution of barium carbonate to which 0.25 mol gfK CO, has been added? Show the dissociation equation, the Ksp expression, and the calculation for determining the barium ion concentration. The Kp for barium carbonate is 5.0 x 10-9.
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- If the molar solubility of Tl2S at 25 oC is 5.31e-08 mol/L, what is the Ksp at this temperature?Ksp = (b) It is found that 9.14e-08 g of Sc(OH)3 dissolves per 100 mL of aqueous solution at 25 oC. Calculate the solubility-product constant for Sc(OH)3.Ksp = (c) The Ksp of Cu3(PO4)2 at 25 oC is 1.40e-37. What is the molar solubility of Cu3(PO4)2?solubility = mol/LCalculate the solubility of BaSO4 with the Ksp = 1.08 x 10-10 ,in an aqueous solution with I = 0.0010 mol kg-1One gram of sodium hydroxide (NaOH) is used to adjust the pH of an aqueous solution (200 gallons) thatcontains 10 lbs of finely ground rhodochrosite (MnCO3) ore. Does the NaOH raise or lower the solutionpH? What is the amount of NaOH added in lbs/ton? What is the molarity (mol/l) of the system? Assumingthe NaOH is completely soluble and the system is at room temperature, what is the solid-to-liquid ratio(wt%) of the system?
- Calculate the solubility (in g/L) of Aluminum sulfide (Al2S3) at 25°C {Ksp for Al2S3 is 1.5x10^-27}. 1) in pure water 2) in 0.10 M H2S solution and in 0.25M Al^+3 solutionThe phosphate in a 3.000-g sample of industrial detergent was precipitated by the addition of 1.000 g of AgNO3. The solution was filtered and filtrate, upon addition of 1.00 mL of 0.01 M fecl3, required 18.23 mL of 0.1377 M KSCN for titration to the end point. (a) the weight percent of phosphate in the detergentCalcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)
- Determine the solubility of KIO4 in water. Volume of saturated KIO4 in conical flask is 25.0 ml,KI is 2g,H2SO4 (3.0M) is 20.0 ml added to KI solution , volume of 0.200 M sodium thiosulphate used for titration is 8.00 ml.and if mean ionic activity co efficient,y+- of KIO4 in the saturated solution is 0.85 ,what is Ksp. .Q: The concentration of the sulphate ion in a mineral water can be determinedby the turbidity which results from the addition of excess BaCl2, to a quantityof measured sample. A turbidometer used for this analysis has been standardisedwith a series of standard solutions of NaSO4. The following resultswere obtained:Standard solution Conc. (SO4)2− (mg/L) Reading of turbidometerS0 0.00 0.06S1 5.00 1.48S2 10.00 2.28S3 15.00 3.98S4 20.00 4.61i. In supposing that a linear relationship exists between the readings takenfrom the apparatus and the sulphur ion concentration, derive an equationrelating readings of the turbidometer and sulphate concentration(method of least squares).ii. Calculate the concentration of sulphate in a sample of mineral waterfor which the turbidometer gives a reading of 3.67.The solubility of AgOH is 2 x 10-8 g/L a) Write a balanced equation for the solubility equilibrium b) Write the expression for the solubility product constant Ksp and calculate its value c) Calculate the pH of a saturated solution of AgOH d) 100 ml of 2.5 x 10-3 SOLUTION of Ag2S04 is added to 100 ml of 2.5 x 10-4 molar NaOH solution. Does a precipitate form? Explain and show calculations to support your answer
- (a) If the molar solubility of Tl2S at 25 oC is 5.31e-08 mol/L, what is the Ksp at this temperature?Ksp = (b) It is found that 1.75e-06 g of Cu3(AsO4)2 dissolves per 100 mL of aqueous solution at 25 oC. Calculate the solubility-product constant for Cu3(AsO4)2.Ksp = (c) The Ksp of BaCO3 at 25 oC is 2.58e-09. What is the molar solubility of BaCO3? solubility = ____ mol/LUsing basic conditions, MnO4- can be used as titrant for the analysis of Mn2+, with both the analyte and the titrant ending up as MnO2. In the analysis of a mineral sample for manganese, a 0.5165-g sample is dissolved, and the manganese is reduced to Mn2+. The solution is made basic and titrated with 0.03358 M KMnO4, requiring 34.88 mL to reach the endpoint. Calculate the %w/w Mn in the mineral sample. Answer: % Mn =Calculate the solubility in grams per 100 ml H2O for La(IO3)3 (s), Ksp= 6.1*10^-12 BaF2 (s), Ksp= 1.8 *10^-7 CaCO3 (s), Ksp=5.0*10^-9 assuming density of water is 1 g/cc