See attached picture. TABLE 13.3 Correlation of H Chemical Shift with EnvironmentChemicalshift (5)Chemicalshift (5)Type of hydrogenType of hydrogenReference(CH) SiSaturatedprimary-CHAlkyl halideX- CI, Br, I0.7-1.32.5-4.0-CH-Saturatedsecondary1.2-1.6Alcohol2.5-5.0(Variable)HAlcohol,ether3.3-4.5Saturatedtertiary1.4-1.8H.H.-H-Vinylic4.5-6.5Allylic1.6-2.2AromaticAr-H6.5-8.0Methylketone2.0-2.4Aldehyde9.7-10.0CHH.AromaticAr-CH2.4-2.7methylCarboxylicacid11.0-12.0Alkynyl-C=C-H2.5-3.0©2004 Thomson - Brooks/Coleo=o= 2) When molecule 2 is treated with HBr and peroxide one major product is formed. Based off of the NMRbelow and the reaction conditions, provide the major product in the box below. If multiple stereoisomers of thatmajor product can be made in the reaction, provide only one of them.a)HBrbenzoyl peroxidemolecule 26H3H3H2H2H1H8.3PPMb) What would you expect the optical rotation of themajor product mixture formed in the reaction frommolecule 2 to be? (circle the correct answer)A Positive orNegative ValueCannot0°Determine

Alkene reacts with HBr in presence of peroxide to form alkyl bromide. In this reaction, the HBr…

2) When molecule 2 is treated with HBr and peroxide one major product is formed. Based off of the NMR below and the reaction conditions, provide the major product in the box below. If multiple stereoisomers of that major product can be made in the reaction, provide only one of them. a) HBr benzoyl peroxide molecule 2 6H 3H 3H 2H 2H 1H PPM b) What would you expect the optical rotation of the major product mixture formed in the reaction from molecule 2 to be? (cirele the correct answer) A Positive or Negative Value Cannot 0° Determine

2) When molecule 2 is treated with HBr and peroxide one major product is formed. Based off of the NMR below and the reaction conditions, provide the major product in the box below. If multiple stereoisomers of that major product can be made in the reaction, provide only one of them. a) HBr benzoyl peroxide molecule 2 6H 3H 3H 2H 2H 1H PPM b) What would you expect the optical rotation of the major product mixture formed in the reaction from molecule 2 to be? (cirele the correct answer) A Positive or Negative Value Cannot 0° Determine

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 4E

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