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- 0.1724g of a mineral containing MnO₂ was dissolved and then treated with excess iodide according to the following unbalanced reaction: MnO2(s) + H+ → Mn²+ + I2 + H₂O The I₂ released was titrated with a solution of Na₂S2O3 0.07320 mol/L, requiring 14.65 mL to reach the point end of degree a) Determine the percentage of MnO₂ in the ore. b) When iodine solutions are used as titrants these are prepared by dissolving 1₂ in concentrated KI. Explain the reason for the need for KI in the preparation of these solutions?Potassium dichromate has several industrial applications. To determine the purity of the salt that will be used in different industrial processes, a sample mass equal to 2.660 g was dissolved and quantitatively transferred to a 500.00 mL flask. An aliquot of 25.00 mL of this solution was treated with excess KI and the released iodine was titrated with 0.1000 mol L-1 sodium thiosulfate, spending 27.00 mL. Calculate the purity of the analyzed salt. Data:K = 39.10 O = 16.00 Cr = 52.00 I = 126.9 S = 32.07Calcium in a 5.00 mL urine sample was precipitated, redissolved and required 16.15 mL of 0.1157 N KMnO4. Calculate the % (w/v) of calcium in the urine.
- Gravimetric analysis of Fe3O4 (MW = 232 g/mole) may be undertaken with the following reactions: Fe3O4 → Fe2O3 → Fe (OH)3. Weight of sample containing 8.00% Fe3O4 that must be taken to obtain a precipitate of Fe(OH)3 (MW = 107 g/mole) that weighs 150 mg is . a. 0.108 g b. 0.325 g c. 1.355 g d. 4.065 g Amount of Fe2O3 (MW = 160 g/mole) from which 150 mg of Fe(OH)3 (MW = 107 g/mole) may be obtained is . a. 0.112 g b. 0.224 g c. 0.448 g d. none of the other choices7. Consider a1Msolution ofNa3AsO4. Write the charge and mass balance equations for this system. (please type answer not write by hend)A potentiometric titration was done using a solution containing 200 mL of water, 20 mL of 3 M sulfuric acid, 5 mL of concentrated phosphoric acid and 10.00 mL of 0.5964 N K2Cr2O7. The amount of titrant added was 19.24 mL of 0.3355 N Fe2+ solution. [H+] = 1.41 x 10-3 M during the titration. Find the concentrations of all species relevant to the redox chemistry present in solution at this point in the titration.
- What is the concentration of ions in the soil solution after fertilizer application? Suppose that 122 pounds of K+ were applied per acre, then a gentle rain soaked the top 10 inches of soil to field capacity, which for the given soil was about 16% water by volume. If the K+ was applied as KCl, it is plausible that it all dissolved and distributed relatively uniformly with the infiltrating water. If so, then what was the K+ concentration in the soil solution in mol K+/L solution? Note that the volume can be computed like we do for an acre-furrow-slice (AFS), as area times depth. This is going to be a relatively small number, so please report your answer in mol K+/L solution to at least 5 decimal places.The mercury in a 0.8142-g sample was precipitated with an excess of paraperiodic acid, H5IO6: 5 Hg 2+ + 2 H5IO6 ---> Hg5(IO6)2 (s) + 10 H + The precipitate (MW = 1448.8 g/mol) was filtered, washed free of precipitating agent, dried, and weighed, and 0.4114 g was recovered. Calculate the a) % Hg (200.6 g/mol) b) % Hg2Cl2 (472.1 g/mol)A Hittorf cell fitted with silver-silver chloride electrodes is filled with HCl solution that contains 0.3856 x 10-3 g HCL per g of water a current of 2 mA is passed for exactly three hours. The solutions are withdrawn, weighed and analysed. Total weight of the anode solution weighs 52.0461 g and contains 0.0133 g of HCl. Calculate the transference number of the H+
- Black-and-white photographic film is coated with silver halides. Because silver is expensive, the manufacturer monitors the Ag⁺ content of the waste stream, [Ag⁺]ᵥᵥₐₛₜₑ, from the plantwith an Ag-selective electrode at 25°C. A stream of known Ag⁺ concentration, [Ag⁺](standard), is passed over the electrode inturn with the waste stream and the data recorded by a computer.(a) Write the equations relating the nonstandard cell potential tothe standard cell potential and [Ag⁺] for each solution.(b) Combine these into a single equation to find [Ag⁺]ᵥᵥₐₛₜₑ.(c) Rewrite the equation from part (b) to find [Ag⁺]ᵥᵥₐₛₜₑ in ng/L.(d) If Eᵥᵥₐₛₜₑ is 0.003 V higher than E(standard), and the standard so-lution contains 1000. ng/L, what is [Ag⁺]ᵥᵥₐₛₜₑ?(e) Rewrite the equation in part (b) to find [Ag⁺]ᵥᵥₐₛₜₑ for a sys-tem in which T changes and Tᵥᵥₐₛₜₑ and T(standard) may be different.A piece of an unknown weighing 12.50is placed in 49.7cm of water in a cylinder. The water level increases to 69.0cm3. whats the calculated value for the drnsity of the solid in g ml-1A 1.000 g sample containing chlorides, iodides and inert materials was treated with dilute nitric acid followed by AgNO3. A precipitate of AgCl (143.32) and AgI (234.77) was produced and weighs 0.9238 g. On heating in a current of Cl2, the AgI is converted to AgCl, and the resulting product weighs 0.7238 g. Find the percentage of a) NaI (149.89) and b) NaCl (58.44) in the sample