2. Ammonia is produced by the Haber process, in which nitrogen and hydrogen are reacted directly using an iron mesh impregnated with oxides as a catalyst. For the reaction N2(g) + 3H2(g)= 2NH3(g) equilibrium constant (Kp values) as a function of temperature are 300 °С, 4.34 х 10-3 500 °С, 1.45 х 10-5 600 °С, 2.25 х 10-6 (a) Is the reaction exothermic or endothermic? Explain why. (b) Calculate AH° from the data using the van't Hoff equation: (K2 In ΔΗ rxn T2. Is the sign of AH° in your answer consistent with your answer for (a)?

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.118PAE
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2. Ammonia is produced by the Haber process, in which nitrogen and hydrogen are reacted
directly using an iron mesh impregnated with oxides as a catalyst. For the reaction
N2(g) + 3H2(g)= 2NH3(g)
equilibrium constant (Kp values) as a function of temperature are
300 °С, 4.34 х 10-3
500 °C, 1.45 х 10-5
600 °C, 2.25 х 10-6
(a) Is the reaction exothermic or endothermic? Explain why.
(b) Calculate AH° from the data using the van't Hoff equation:
AHrxn
K2
In
\K.
R
\71
T2
Is the sign of AH° in your answer consistent with your answer for (a)?
Transcribed Image Text:2. Ammonia is produced by the Haber process, in which nitrogen and hydrogen are reacted directly using an iron mesh impregnated with oxides as a catalyst. For the reaction N2(g) + 3H2(g)= 2NH3(g) equilibrium constant (Kp values) as a function of temperature are 300 °С, 4.34 х 10-3 500 °C, 1.45 х 10-5 600 °C, 2.25 х 10-6 (a) Is the reaction exothermic or endothermic? Explain why. (b) Calculate AH° from the data using the van't Hoff equation: AHrxn K2 In \K. R \71 T2 Is the sign of AH° in your answer consistent with your answer for (a)?
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