The molar volume of a solid is 142 cm3/mol at 1 atm and 427 K which is its melting temperature. The molar volume of the liquid at this temperature and pressure is 153 cm3/mol. At 1.2 MPa the melting temperature changes to 429 K. Calculate the enthalpy and entropy of fusion of the solid using the integrated form of the clapeyron equation
The molar volume of a solid is 142 cm3/mol at 1 atm and 427 K which is its melting temperature. The molar volume of the liquid at this temperature and pressure is 153 cm3/mol. At 1.2 MPa the melting temperature changes to 429 K. Calculate the enthalpy and entropy of fusion of the solid using the integrated form of the clapeyron equation
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter6: Equilibria In Single-component Systems
Section: Chapter Questions
Problem 6.41E
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2. The molar volume of a solid is 142 cm3/mol at 1 atm and 427 K which is its melting temperature. The molar volume of the liquid at this temperature and pressure is 153 cm3/mol. At 1.2 MPa the melting temperature changes to 429 K. Calculate the enthalpy and entropy of fusion of the solid using the integrated form of the clapeyron equation
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