2. Why can an organometallic complex perform the reactions such as insertion where normal coordination complex could not perform? Because the presence of d-orbitals in the metal centre. Because of the intramolecular pi-electron charge transfer in the ligand. Because of the metal to ligand pi-electron charge transfer. Because of the intermolecular pi-electron charge transfer in the ligand.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 33P
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2.
Why can an organometallic complex perform the reactions such as insertion where
normal coordination complex could not perform?
Because the presence of d-orbitals in the
metal centre.
Because of the intramolecular pi-electron
charge transfer in the ligand.
Because of the metal to ligand pi-electron
charge transfer.
Because of the intermolecular pi-electron
charge transfer in the ligand.
Transcribed Image Text:2. Why can an organometallic complex perform the reactions such as insertion where normal coordination complex could not perform? Because the presence of d-orbitals in the metal centre. Because of the intramolecular pi-electron charge transfer in the ligand. Because of the metal to ligand pi-electron charge transfer. Because of the intermolecular pi-electron charge transfer in the ligand.
Select which species below can
undergo B-elimination.
[RhPh(C3H7)2(PME3)4]
[RhH(C=CH)2(PMe3)4]
O [SCH(C=CH)2(PM:3)]
[ScPh(C3H7)2(PMe3)]
Transcribed Image Text:Select which species below can undergo B-elimination. [RhPh(C3H7)2(PME3)4] [RhH(C=CH)2(PMe3)4] O [SCH(C=CH)2(PM:3)] [ScPh(C3H7)2(PMe3)]
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