20% H2SO4 L added Au1 i

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter10: Atomic Emission Spectrometry
Section: Chapter Questions
Problem 10.11QAP
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Gold can be determined in solutions containing high concentrations of diverse ions by ICP-AES. Aliquots of
50.0 mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was
prepared containing 10.0 mg/L Au in 20% H2SO4 and quantities of this solution were added to the sample
solutions to give 0, 2.5, 5, and 10 mg/L added Au in each of the flasks. The solutions were made up to a total
volume of 100.0 mL, mixed, and analysed by ICP-AES. The resulting data are presented in the following table.
Added Au, mg/L
Emission Intensity Count
12,568
19,324
26,622
40,021
0.0
2.5
5.0
10.0
Calculate the concentration of gold in the original sample.
Transcribed Image Text:Gold can be determined in solutions containing high concentrations of diverse ions by ICP-AES. Aliquots of 50.0 mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was prepared containing 10.0 mg/L Au in 20% H2SO4 and quantities of this solution were added to the sample solutions to give 0, 2.5, 5, and 10 mg/L added Au in each of the flasks. The solutions were made up to a total volume of 100.0 mL, mixed, and analysed by ICP-AES. The resulting data are presented in the following table. Added Au, mg/L Emission Intensity Count 12,568 19,324 26,622 40,021 0.0 2.5 5.0 10.0 Calculate the concentration of gold in the original sample.
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