21,22,23,25

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter7: Molecular Structures
Section: Chapter Questions
Problem 102QRT: There are two compounds with the molecular formula HN3. One is called hydrogen azide; the other is...
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21,22,23,25
8
e.
10
20. Identify the size of the hydrocarbon that is used in jet fuel.
a. C₁-C4
b. C5-C12
C. C12- C18
d. C20 and higher nonvolatile liquids
e. C20 and higher nonvolatile solids
21. Which of the following is the correct Newman projection for the following compound as viewed
down the indicated bond in the conformation shown?
cl
H₂
CI.H
H..9
CI
CH3
Br
· CH3
H.
CI
CH3
CI
Br
CH3
H*
y
ABCDE
CH3-
B.
1
CH3
11
CH
Br
CH3
CH3
CH3
a. I
b. Il
d. IV
e. V
22. Which of the following is a Newman projection of a staggered conformation for ethane?
H
HH
H
HCH3
HCH3
-CH3
H
CH3
H
Hy
H
HH
H
H
H
H
IV
V
23. Consider the energy diagram showing the conformational analysis of propane and match the
indicated position with the correct conformation below.
H
CH₂
H
CH3
CH3
CI
Br
CI
Br
CI
H
CH3
CI
Br
H
CI
Transcribed Image Text:8 e. 10 20. Identify the size of the hydrocarbon that is used in jet fuel. a. C₁-C4 b. C5-C12 C. C12- C18 d. C20 and higher nonvolatile liquids e. C20 and higher nonvolatile solids 21. Which of the following is the correct Newman projection for the following compound as viewed down the indicated bond in the conformation shown? cl H₂ CI.H H..9 CI CH3 Br · CH3 H. CI CH3 CI Br CH3 H* y ABCDE CH3- B. 1 CH3 11 CH Br CH3 CH3 CH3 a. I b. Il d. IV e. V 22. Which of the following is a Newman projection of a staggered conformation for ethane? H HH H HCH3 HCH3 -CH3 H CH3 H Hy H HH H H H H IV V 23. Consider the energy diagram showing the conformational analysis of propane and match the indicated position with the correct conformation below. H CH₂ H CH3 CH3 CI Br CI Br CI H CH3 CI Br H CI
nú
180
180
dihedral angle
HH
H.
H
HH
H
11
Geue
CH3
H
CH3
HCH3
HH
H
H
H
IV
|||
E.
24. Which of the following is a gauche conformation for butane?
HCH3
HCH3
CH3
H CH3
HH
CH3
H
CH3
H Η
H.
CH3
CH3 CH3
H
H
|||
11
25. What is the eclipsing cost of Br and H if the energy difference between the staggered and
eclipsed conformations of bromoethane, shown in the box below, is 13 kJ/mol?
Br
H
CH3
===>>
ABCDE
A.
B.
IV
D.
I
==>
CH3
H
H
HCH3
HH
H
V
CH3
Transcribed Image Text:nú 180 180 dihedral angle HH H. H HH H 11 Geue CH3 H CH3 HCH3 HH H H H IV ||| E. 24. Which of the following is a gauche conformation for butane? HCH3 HCH3 CH3 H CH3 HH CH3 H CH3 H Η H. CH3 CH3 CH3 H H ||| 11 25. What is the eclipsing cost of Br and H if the energy difference between the staggered and eclipsed conformations of bromoethane, shown in the box below, is 13 kJ/mol? Br H CH3 ===>> ABCDE A. B. IV D. I ==> CH3 H H HCH3 HH H V CH3
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