22.48 Draw the product formed when phenylacetic acid (CsHsCH,COOH) is treated with each reagent. With some reagents, no reaction occurs. а. NaHCO, b. NaOH c. SOCI, d. NaCI e. NH3 (1 equiv) f. NH3, A g. CH;OH, H,SO, h. CH;OH, "OH i. [1] NaOH; (2] CH,COCI j. CH,NH2, DCC k. [1] SOC,; (2] CH;CH,CH,NH2 (excess) 1. [1) SOC; [2] (CHCHOH ANSWERS 22.48 CSHŞCH2COOH abon NaHCO3 CH,OH H2SO4 a. + H2CO3 g. OCH3 O Nat CH3OH h. + H2O NaOH b. HO- O Na (1] NaOH SOCI, i. (2] CH;COCI С. CI NaCl d. no reaction j. CH;NH, DCC `NHCH, NH3 (1) SOCI2 k. е. (1 equiv) O- NH (2) CH;CH,CH;NH2 NHCH,CH,CH, [1] NH3 [2] A f. I. [1) SOCI2 NH2 [2) (CH3)2CHOH OCH(CH3)2
22.48 Draw the product formed when phenylacetic acid (CsHsCH,COOH) is treated with each reagent. With some reagents, no reaction occurs. а. NaHCO, b. NaOH c. SOCI, d. NaCI e. NH3 (1 equiv) f. NH3, A g. CH;OH, H,SO, h. CH;OH, "OH i. [1] NaOH; (2] CH,COCI j. CH,NH2, DCC k. [1] SOC,; (2] CH;CH,CH,NH2 (excess) 1. [1) SOC; [2] (CHCHOH ANSWERS 22.48 CSHŞCH2COOH abon NaHCO3 CH,OH H2SO4 a. + H2CO3 g. OCH3 O Nat CH3OH h. + H2O NaOH b. HO- O Na (1] NaOH SOCI, i. (2] CH;COCI С. CI NaCl d. no reaction j. CH;NH, DCC `NHCH, NH3 (1) SOCI2 k. е. (1 equiv) O- NH (2) CH;CH,CH;NH2 NHCH,CH,CH, [1] NH3 [2] A f. I. [1) SOCI2 NH2 [2) (CH3)2CHOH OCH(CH3)2
Chapter28: Biomolecules: Nucleic Acids
Section28.SE: Something Extra
Problem 38AP
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explain and show step by step how the product formed when phenyacetic acid is treated with reagents in letter L and K only. this is about carboxylic acid and its derivatives
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